In one sentence, we are interested in the spectroscopic characterization of surface chemical processes. The aim of our research group is to understand the mechanistic steps and to control heterogeneous surface/interface processes, such as alcohol oxidation, CH4 and CO2 dissociation, as well as electrochemical oxidation, on important metal oxide surfaces at near-ambient condition. A novel spectroscopic approach utilizing surface-specific vibrational sum frequency generation (VSFG), ultrafast transient absorption (fs-TA) and an electrochemical impedance spectroscopy (EIS) has been designed.
- VSFG, a second-order nonlinear process sensitive only to surface and/or interfacial phenomena, will monitor in-situ adsorption, dissociation, oxidation and charge transfer processes at various gas-solid, liquid-solid and solid-solid interfaces.
- Ultrafast fs-TA will characterize the dynamics of electron, hole recombination and transfer process on a catalyst modified metal oxide photoanodes.
- Spectro-electrochemistry approach by combining VSFG, EIS and basic electrochemistry to study the kinetics governing the intercalation and de-intercalation mechanisms at the electrode-electrolyte interface to develop better secondary ion batteries.