Publication Details:
Title: Triallyl(aryl)silanes serve as a convenient agent for silicon-based cross-coupling reaction of aryl halides
| Author(s) | Yoshiaki Nakao, TakuroOda, Akhila K. Sahoo, TamejiroHiyama : Journal of Organometallic Chemistry, 2003, 687, 570-573. |
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| Journal Name | Journal of Organometallic Chemistry |
More Details:
Triallyl(aryl)silanes, stable and easily accessible arylsilanes, were found to react with aryl bromides in the presence of a palladium catalyst (PdCl2–PCy3) and tetrabutylammonium fluoride (TBAF) in good yields. The scope of the reaction is broad, and a wide variety of functional groups are tolerant. Allyl groups on Si are readily cleaved upon treatment with TBAF to form fluorosilanes, silanepolyols, siloxanes and/or their mixed forms, which might be responsible for high efficiency of the reaction.
https://www.sciencedirect.com/science/article/pii/S0022328X03009197?via%3Dihub