Publication Details:
Title: [3 + 2]-Cycloaddition of Nonstabilized Azomethine Ylides. 10. An Efficient Strategy for the Construction of x-Azatricyclo[m.n.0.0a,b]alkanes by Intramolecular Cycloaddition of Cyclic Azomethine Ylide
| Author(s) | Ganesh Pandey*, Akhila K. Sahoo, and Trusar D. Bagul : Org. Lett., 2000, 2, 2299-2301 |
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| Journal Name | Organic Letters |
More Details:
Various new structural entities related to x-azatricyclo[m.n.0.0a,b]alkanes are constructed by the intramolecular [3 + 2] dipolar cycloaddition of nonstabilized cyclic azomethine ylides. The ylide is generated by the sequential double desilylation of N-alkyl α,α‘-bis(trimethylsilyl)cyclic amines using Ag(I)F as a one-electron oxidant.