1. Movie of evolution of the wave packet porbability density (for first 13 fs) on the lower or upper adiabatic sheets of the 2pE' electronic ground manifold of D3 is presented here as ".gif" file. Contours lines in orange and blue colors, respectively, correspond to the potential energy surface and wave packet probability.

    Evolution on lower surface under strict BO appoximation


    Evolution on lower surface with inclusion of GP correction


    Evolution on lower surface with inclusion of BH correction


    Evolution on lower surface with inclusion of both GP and BH corrections


    Evolution on upper surface under strict BO appoximation


    Evolution on upper surface with inclusion of GP correction


    Evolution on upper surface with inclusion of BH correction


    Evolution on upper surface with inclusion of both GP and BH corrections


  2. Movie of evolution of the porbability density (for first 13 fs) of the two components of the adiabatic wavepacket on the coupled manifold of the 2pE' electronic state of D3 is presented here as ".gif" file. Complete surface coupling is included here using diabatic approach. (Components of the adiabatic wavepacket corresponding to the lower and upper adiabatic sheet are ploted, respectively, in the left and right panels. Lower pannels shows the norm or the adiabatic electronic population of these two components.)

    Evolution on coupled manifold when initial WP is launched on the upper adiabatic sheet


    Evolution on coupled manifold when initial WP is launched on the lower adiabatic sheet