Publications
2024
208. Parvathy M. Unnikrishnan, Olivia Basu, Rajendar Nasani and Samar K. Das*
Giant {Mo132}-Polyoxometalate Isolated with Diverse Organic Cations: A Systematic Proton Conductivity Study
Dalton Trans. 2024,Just accepted.
207. Parvathy M. Unnikrishnan, Gopika Premanand and Samar K. Das*
Polyoxometalate Driven Assembly of Inorganic-Organic Hybrid Materials: Proton Conductivity Studies
J. Chem. Sci. 2024, Just accepted.
206. Gopika Premanand, Debu Jana and Samar K. Das*
Oxidation of Ni(H2O)6@MoO3 to Ni2O3/MoO3 Composites by Aerial Annealing: Electrocatalytic Hydrogen Evolution
Chem. Asian J. 2024, e202401172.
205. Debu Jana, Gopika Premanand, Devika Chandran, Bharat Kumar Tripuramallu and Samar K. Das*
A Proton Conductive Co(II)-Polyoxometalate Acts as a Precatalyst for Efficient Electrocatalytic Water Oxidation
Inorg. Chem. 2024, 63, 18797−18808.
204. Debu Jana, Mohammed Alamgir and Samar K. Das*
Synergy of {Co(H2O)6}2+ with a Polyoxometalate Leads to Aqueous Homogeneous Hydrogen Evolution: Experiments and Computations
Inorg. Chem. 2024, 63, 13959-13971.
203. Gopika Premanand, Debu Jana, Parvathy M. Unnikrishnan and Samar K. Das*
Hexagonal Mo-Bronze: Single Crystal Structures, Electrocatalytic Hydrogen Evolution and Proton Conductivity.
Inorg. Chem. 2024, 63, 10671-10681.
202. Debu Jana, Shalini Sanjay Mishra and Samar K. Das*
Intercalating Potassium-aqua Complex Cation into α-MoO3 Layer Without Reducing Molybdenum : A Potential Storage System
Chem. Commun. 2024,60, 5439-5442.
201. Nilanjan Mukherjee, Anupam Das, Subhabrata Mukhopadhyay, Samar K. Das* and Tushar Jana*
Grafting of Polymer Brushes on MOF Surface to Achieve Proton Conducting Membranes
ACS Appl. Polym. Mater. 2024, 6, 846-858.
200. Athira Ravi, Ratri Biswas, Sarbani Das and Samar K. Das*
Exploring Proton Conductivity Studies of a Copper based Hydroxylated Polyoxometalate
J. Chem. Sci. 2024, 136, Article No. 3.
2023
199. Sateesh Mulkapuri,Asha Siddikha, Athira Ravi, Pinki Saha, Avulu Vinod Kumar, Sathyanarayana Boodida, Muga Vithal and Samar K. Das*
Electrocatalytic Hydrogen Evolution by a Uranium(VI) Polyoxometalate: An environmental Toxin for Sustainable Energy Generation
Inorg. Chem. 2023, 62, 19664-19676.
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198. Olivia Basu, Anupam Das, Tushar Jana* and Samar K. Das*
Designing of Flexible Metal-Organic Framework-based Super-protonic Conductors and their Fabrication with a Polymer into Proton Exchange Membranes
ACS Appl. Energy. Mater. 2023, 6, 9092-9107 .
197. Athira Ravi, Sateesh Mulkapuri and Samar K. Das*
Hydroxylated Polyoxometalate with Cu(II)- and Cu(I)- Aqua Complexes: A Bifunctional Catalyst for Electrocatalytic Water Splitting at Neutral pH
Inorg. Chem, 2023, 62, 12650-12663.
196. Debu Jana, Hema Kumari Kolli and Samar K. Das*
Co(OH)2 Intercalated in MoO3 by Molecular Electrodeposition Resulting in a Conductive Material: A Molybdenum Bronze for Efficient Electrocatalytic Hydrogen Evolution.
Chem. Mater., 2023, 35, 3083-3094 .
195. Mukara RamaThulasamma, Suresh Bommakanti and Samar K. Das*
Diverse Coordination Architectures based on a Flexible Multidentate Carboxylate Ligand and N-donor Linkers: Synthesis, structure, Supramolecular Chemistry and Related Properties
Polyhedron, 2023, 230, Article No.116216 .
2022
194. N. Tanmaya Kumar, Shivaiah Vaddypally, and Samar K. Das*
A Rearrangement Reaction to Yield NH4+ Ion Driven by Polyoxometalate Formation
ACS Omega,2022,7, 31474-31481.
193. Sateesh Mulkapuri, Athira Ravi, Rajendar Nasani, Sathish Kumar Kurapati and Samar K. Das*
Barrel-Shaped-Polyoxometalates Exhibiting Electrocatalytic Water Reduction at Neutral pH: A Synergy Effect
Inorg. Chem. 2022, 61, 13868-13882.
192. Olivia Basu, Subhabrata Mukhopadhyay, Subhajit Laha and Samar K. Das*
Defect Engineering in a Metal-Organic Framework System to Achieve Super-Protonic Conductivity
Chem. Mater. 2022, 34, 6734-6743.
191. Sateesh Mulkapuri, Athira Ravi, Subhabrata Mukhopadhyay, Sathish Kumar Kurapati, Vinaya Siby and Samar K. Das*
W
VI‒OH Functionality on polyoxometalates for water reduction to molecular hydrogen
Inorg. Chem. Front., 2022, 9, 3566-3577.
190. Athira Ravi, Rajendar Nasani and Samar K. Das*
Cobalt Formate, a Functional MOF: Electrocatalytic Water Oxidation
Journal of Molecular and Engineering Materials, 2022, 10, 2240002.
189. Sateesh Mulkapuri, Athira Ravi and Samar K. Das*
Fabricating a Functionalized Polyoxometalate with ZIF-8: A Composite Material for Water Oxidation in a Wide pH Range
Chem. Mater. 2022, 34, 3624−3636.
188. Kumar Biradha*, Samar K. Das, and Xian-He Bu
Coordination Polymers as Heterogeneous Catalysts for Water Splitting and CO
2 Fixation
Cryst. Growth Des. 2022, 22, 2043−2045.
187. Debu Jana, Hema Kumari Kolli and Samar K. Das*
Single Crystals of α-MoO
3 Intercalating {Ni(H
2O)
6}
2+ and Electrocatalytic Water Reduction: Towards a Class of Molybdenum Bronzes
Inorg. Chem., 2022, 61, 3816-3820.
2021
186. Mukara Ramathulasamma, Suresh Bommakanti and Samar K. Das*
A 'two-in-one' crystal having two different dimensionality in the extended structures: a series of cadmium(II) coordination polymers from V-shaped organic linkers
Polyhedron, 2021, 210, Article No. 115508 .
185. Hema Kumari Kolli, Debu Jana and Samar K. Das*
Nano-blackberries of {W
72Fe
33} and {Mo
72Fe
30}: Electrocatalytic Water Reduction
Inorg. Chem., 2021, 60, 15569 - 15582 .
184. Olivia Basu, Subhabrata Mukhopadhyay, Avik De, Anupam Das and Samar K. Das*
Tuning electrochemical and catalytic ORR performance of C
60 by its encapsulation in ZIF-8: a solid-state analogue of dilute fullerene solution
Materials Chemistry Frontiers, 2021, 5, 7654 - 7665 .
183. Debu Jana, Hema Kumari Kolli, Subhashree Sabnam and Samar K. Das*
Efficient homogeneous electrocatalytic hydrogen evolution using a Ni-containing polyoxometalate catalyst
Chem. Commun., 2021, 57, 9910 - 9913 .
182. Chandani Singh, Atanu Haldar, Olivia Basu and Samar K. Das*
Devising a Polyoxometalate based Functional Material as an Efficient Electrocatalyst for Hydrogen Evolution Reaction
Inorg. Chem., 2021, 60, 10302 - 10314 .
181. Chandani Singh and Samar K. Das*
Polyoxometalate Based Hybrid Compound as a Pre-catalyst for Electrocatalytic Water Reduction at Neutral pH
J. Chem. Sci., 2021, 133, 81 .
180. Ramakrishna Bodapati, Gaurav Ranjan Dey, Gunjan R Ramteke, Katturi Naga Krishnakanth, S Venugopal Rao, KV Jovan Jose*, Samar K Das*
Carbazole-Based π-Conjugated 2, 2'-Bipyridines, a New Class of Organic Chromophores: Photophysical, Ultrafast Nonlinear Optical and Computational Studies
Dyes and Pigments, 2021, 185, Article No. 108932.
2020
179. Subhabrata Mukhopadhyay, Olivia Basu and Samar K. Das*
ZIF-8 MOF Encapsulated Co-porphyrin, an Efficient Electrocatalyst for Water Oxidation in a Wide pH Range: Works Better at Neutral pH
ChemCatChem 2020, 12, 5430-5438.
178. Subhabrata Mukhopadhyay, Olivia Basu, Rajendar Nasani and Samar K. Das*
Evolution of metal organic frameworks as electrocatalysts for water oxidation
Chem. Commun., 2020, 56, 11735-11748. (Feature Article)
177. Subhabrata Mukhopadhyay, Anupam Das, Tushar Jana* and Samar K. Das*
Fabricating a MOF Material with Polybenzimidazole into an Efficient Proton Exchange Membrane
ACS Applied Energy Materials, 2020, 3, 7964-7977.
176. Vedichi Madhu*, Arun Kumar Kanakati and Samar K. Das*
Serendipitous isolation of triazinone based air stable organic radical: synthesis, crystal structure and computation
New J. Chem. 2020, 44, 10781-10785 .
175. N Tanmaya Kumar, Umashis Bhoi, Pragya Naulakha and Samar K. Das*
A Polyoxometalate Supported Copper Dimeric Complex: Synthesis, Structure and Electrocatalysis
Inorg. Chim. Acta 2020, 506, article no. 119554 .
174. Olivia Basu and Samar K. Das*
Supramolecular inorganic chemistry leading to functional materials (A Review Article)
J. Chem. Sci., 2020, 132, 46 DOI: doi.org/10.1007/s12039-020-1744-0 .
173. Subhabrata Mukhopadhyay, Olivia Basu, Aranya Kar and Samar K. Das*
Efficient Electrocatalytic Water Oxidation by Fe(salen)- MOF Composite: Effect of modified microenvironment
Inorg. Chem., 2020, 59, 472-483 .
2019
172. Sateesh Mulkapuri, Sathish Kumar Kurupati, Subhabrata Mukhopadhyay and Samar K. Das*
A fully reduced {V
18IVO
42} host and VO
43-, Cl
- as guest anions: synthesis, characterization and proton conductivity
New J. Chem., 2019, 43, 17670-17679 .
171. Chandani Singh and Samar K. Das*
Anderson polyoxometalate supported Cu(H
2O)(phen) complex as an electrocatalyst for hydrogen evolution reaction in neutral medium
Polyhedron, 2019, 172, 80-86 DOI: doi.org/10.1016/j.poly2019.03.026 .
170. Suresh Bommakanti and Samar K. Das*
A Two-dimensional Metal-Organic-Framework Formed from a Cobalt(II) Ion and a Bifunctional Ligand Exhibiting Thermochromic Behaviour
Frontiers in Materials, 2019, 6, Article Number 170 doi: 10.3389/fmats.2019.00170 .
169. Ramakrishna Bodapati, Chakradhar Sahoo, Mahesh Gudem and Samar K. Das*
Mononuclear Ru(II) Complexes of an Arene and Asymmetrically Substituted 2,2' - Bipyridine Ligands: Photophysics, Computation and NLO Properties
Inorg. Chem., 2019, 58, 11470-11479 .
168. Sateesh Mulkapuri, Sathish Kumar Kurupati and Samar K. Das*
Carbonate encapsulation from dissolved atmospheric CO
2 into a polyoxovanadate capsule
Dalton Trans., 2019, 48, 8773-8781 .
167. Subhabrata Mukhopadhyay, Joyashish Debgupta, Chandani Singh, Rudraditya Sarkar, Olivia Basu and Samar K. Das*
Designing of UiO-66 Based Super Protonic Conductor with the Highest MOF Based Proton Conductivity
ACS Appl. Mater. Interfaces 2019, 11, 13423−13432.
166. Bommakanti Suresh and Samar K. Das*
A quantitative transmetalation with a metal organic framework compound in a solid-liquid interface reaction: synthesis, structure, kinetics, spectroscopy and electrochemistry
CrystEngComm, 2019, 21, 2438 - 2446
165. Bommakanti Suresh, Uppari Venkataramudu and Samar K. Das*
Functional Coordination Polymers from a Bifunctional ligand: A Quantitative Transmetalation via Single Crystal to Single Crystal Transformation
Crystal Growth & Design, 2019, 19, 2, 1155-1166
164. Ramababu Bolligarla, Gummadi Durgaprasad and Samar K. Das*
Coordination polymers from dithiolato complexes and alkali metal cations: How a crystallizing and coordinating solvent influences the dimensionality
Inorganic Chimica Acta, 2019, 486, 412-424
2018
163. A. Srinivasa Rao and Samar K. Das*
A Versatile Polyoxovanadate in Diverse Cation Matrices: A Supramolecular Perspective
Frontiers in Chemistry, Inorganic Chemistry. 2018, 6:469 doi: 10.3389/fchem.2018.00469
162. Paulami Manna, M. Ramathulasamma, B. Suresh and Samar K. Das*
Metallo-macrocycles from a library of felexible linkers: 1D cobalt(II) coordination polymers and a supramolecular pipe
Polyhedron, 2018, 151, 394-400 DOI: 10.1016/j.poly.2018.05.047
161. Olivia Basu, Subhabrata Mukhopadhyay and Samar K. Das*
Cobalt based functional inorganic materials: electrocatalytic water oxidation
J. Chem. Sci., 2018, 130, Article No. 93
160. Chandani Singh, Subhabrata Mukhopadhyay and Samar K. Das*
Polyoxometalate Supported Bis(bpy)mono(aqua)Ni(II) Coordination Complex: an Efficient Electrocatalyst for Water Oxidation
Inorg. Chem. 2018, 57, 6479-6490 DOI: 10.1021/acs.inorgchem.8b00541
159. I. Krishna Naik, B. Ramakrishna, Rudraditya Sarkar, Navendu Mondal and Samar K. Das*
Functional Molecular System of Bis(pyrazolyl)pyridine Derivatives: Photo-physics, Spectroscopy, Computation and Ion Sensing
ACS Omega, 2018, 3, 3022-3035
158. V. Shivaiah, N Tanmaya Kumar and Samar K. Das*
A Gas-Liquid Interface Synthesis in Polyoxometalate Chemistry: Potential Bag Filter For Volatile Organic Amines
J. Chem. Sci., 2018, 130, Article No. 37
157. Subhabrata Mukhopadhyay, Joyashish Debgupta, Chandani Singh, Aranya Kar and Samar K. Das*
A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ZIF-8,an Efficient and Robust Electrocatalyst
Angew. Chem. Int. Ed. 2018, 57, 1918-1923. DOI: 10.1002/anie.201711920
2017
156.T Arumuganathan, Asha Siddikha and Samar K. Das*
‘Ionic crystals’ consisting of trinuclear macrocations and polyoxometalate anions exhibiting single crystal to single crystal transformation: breathing of crystals
J. Chem. Sci. 2017, 129, 1121-1142
155.Sridevi Yerra and Samar K. Das*
Organic Free Decavanadate Based Materials: Inorganic Linkers to Obtain Extended Structures
Journal of Molecular structure, 2017, 1146, 23-31 DOI: 10.1016/j.molstruc.2017.05.097
154.Suranjana Bose, Joyashish Debgupta, Rani M. Ramsundar and Samar K. Das*
Electrochemical Water Oxidation Catalyzed by an ‘in-situ’ Generated α-Co(OH)
2 Film on Zeolite-Y Surface
Chemistry- A European Journal, 2017, 23, 8051-8057 DOI: 10.1002/chem.201700955 (HOT PAPER)
153.Indravath Krishna Naik, Rudraditya Sarkar, Vedichi Madhu, Ramababu Bolligarla, Ravada Kishore, and Samar Kumar Das*
An Organic Receptor Isolated in an Unusual Intermediate Conformation: Computation, Crystallography and Hirshfeld Surface Analysis
J. Phys. Chem. A, 2017, 121, 3274-3286.
152.Girijesh Kumar, Ramu Guda, Ahmad Husain, Ramakrishna Bodapati and Samar K. Das*
A Functional Zn(II)-Metallacycle Formed from an N-Heterocyclic Carbene Precursor: A Molecular Sensor for Selective Recognition of Fe
3+ and IO
4–
Ions and spectroscopy
Inorg. Chem., 2017, 56, 5017-5025.
151.Tanmay Chatterjee, N Tanmaya Kumar and Samar K Das
A planar anthracene-imidazolium / anthracene-benzimidazolium cation system in a spherical polyoxometalate matrix: synthesis, crystallography
and spectroscopy
Polyhedron, 2017, 127, 68-83 DOI: 10.1016/j.poly.2017.01.049
150. Girijesh Kumar and Samar K. Das
Coordination Frameworks/ Networks Containing Compounds as Catalysts
Inorganic Chemistry Frontiers, 2017, 4, 202 - 233 DOI: 10.1039/C6QI00358C
2016
149. Raju Mekala, Sabbani Supriya and Samar K. Das
Isolation of Blackberry-shaped Nano-particles of Giant {Mo
72Fe
30} Cluster and their Transformation to Crystalline Nano-Ferric Molybdate,
Inorg. Chem. 2016, 55, 12504−12507.
148. Vedichi Madhu, Ramababu Bolligarla, Indravath K. Naik, Raju Mekala and Samar K. Das
A {Cu
4I
4} Cluster Supported on a Metal-dithiolate Complex Anion Causes its Conformational Change Leading to a Doubly-bridged Curved
Coordination Polymer and its Reactivity with a Diamine Resulting in the Emergence of a [M(diammine)(dithiolate)] System
Eur. J. Inorg. chem. 2016, 4257.
147. Monima Sarma, Tanmay Chatterjee, Ramakrishna Bodapati, Katturi Krishnakanth, Syed Hamad, Rao Venugopal and Samar K. Das
Cyclometalated Iridium(III) Complexes Containing 4,4' π Conjugated 2,2' bipyridine Derivatives as the Ancillary Ligands: Synthesis, Photophysics and
Computational Studies
Inorg. Chem, 2016, 55, 3530
146. Paulami Manna, Joyashish Debgupta, Suranjana Bose and Samar K. Das
A Mononuclear Co(II) Coordination Complex Locked in a Confined Space Acting as an Electrochemical Water Oxidation Catalyst: A Ship in a Bottle
Approach.
Angew. chem. Int. Ed 2016, 55, 2425
2015
145. Ramakrishna Bodapati, Monima Sarma, Arunkumar Kanakati and Samar K. Das
Asymmetrically Substituted and pi-Conjugated 2,2'-Bipyridine Derivatives: Synthesis, Spectroscopy, Computation and Crystallography
J. Org. Chem. 2015, 80, 12482.
144. Indravath K. Naik, Rudraditya Sarkar, S. K. Das
Nickel(III)-bis(quinoxaline-dithiolato) Complexes, [Bu
4N][NiIII(6,7-qdt)
2] and [PPh
4][NiIII(ph
2-6,7-qdt)
2].CHCl
3 (6,7-qdt=quinoxalene-6,7-dithiolate;
Ph
26,7-qdt=phenyl quinoxaline-6,7-dithiolate): Synthesis, Spectroscopy, Electrochemistry, DFT Calculations, Crystal Structures
and Hirshfeld Surface Analysis
Eur. J. Inorg. Chem., 2015, 5523.
143. Ravada Kishore, Bharat Kumar Tripuramallu, S. K. Das
Significant Role of Supramolecular Interactions on Conformational Modulation of Flexible Organic Cation Receptors in a Metal-bis(dithiolate)
Coordination complex Matrix
Cryst. Growth Des, 2015, 15, 4459.
142. Sabbani Supriya and S. K. Das
Reversible solid to solid transformation in a crystalline state gas-solid reaction at an ambient condition: Fe-N(pyridine) bond formation at the expense
of Fe-OH
2 bond breaking and vice versa
Cryst Eng. Commun, 2015, 17, 8850.
141. Vedichi Madhu, Sabbani Supriya, Kishore Ravada, Indravath K. Naik, S. K. Das
Mechanical motion in the solid state and molecular recognition: reversible cis-trans transformation of an organic receptor in a solid-liquid crystalline
state reaction triggered by anion exchange
Cryst Eng. Commun, 2015, 17, 3219.
140. Paulami Manna, S. K. Das
A Perceptive Approach in Assessing Rigidity versus Flexibility in the Construction of Diverse Metal-Organic Coordination Networks: Synthesis,
Structure and Magnetism
Cryst. Growth Des, 2015, 15, 1407.
139. Gummadi Durgaprasad, S. K. Das
Modelling the active site of [FeFe]-hydrogenase: Electro-catalytic hydrogen evolution from acetic acid catalysed by [Fe
2(μ-L)(CO)
6] and
[Fe
2(μ-L)(CO)
5(PPh
3)] (L=pyrazine-2,3-dithiolate, quinoxaline-2,3-dithiolate and pyrido[2,3-b]pyrazine-2,3-dithiolate)
Journal of Chemical sciences, 2015,127, 295.
138. Paulami Manna, Bharat Kumar Tripuramallu, Suresh Bommakanti, S. K. Das
Synthesis, Characterization and Magnetism of Metal-Organic Compounds: Role of Positions of the Coordinating Groups of a Meso-flexible Ligand
in Placing Anisotropy to Exhibit Spin-Canting Behaviour
Dalton Trans., 2015, 44, 2852.
2014
137. Srinivas Rao Amanchi, Anjali Patel, S. K. Das
Polyoxometalate coordinated transition metal complexes as catalysts: oxidation of styrene to benzaldehyde/benzoic acid
Journal of Chemical sciences, 2014, 126, 1641.
136. Shivaiah Vaddypally, Tanmay Chatterjee, S. K. Das
Coordination of lanthanide cation to an anderson type polyoxometalate anion leads to isomorphous metal-oxide based one-dimentional inorganic
solids: synthesis, crystal structure and spectroscopy
Journal of Chemical sciences, 2014, 126, 1525.
135. Bharat Kumar Tripuramallu, Paulami Manna, S. K. Das
Supramolecular interactions mediated conformational modulation of flexible linker leading to the isolation of ametallo-macrocycle in a
polyoxometalate matrix : hirshfeld surfaces and 2d fingerprint plots
Cryst Eng. Commun, 2014, 16, 10300.
134. M.Sivasankar Reddy, Y. Sarala, M. Jagadeesh, S. K. Das and A. Varada Reddy
5-Hydroxy-2-nitrobenzaldehyde thiosemicarbazone (HNBATSC)
Acta Crystallographica., E, 2014, 70, o846.
133. Sridevi Yerra, Bharat Kumar Tripuramallu, S. K. Das
Decavanadate-based discrete compound and coordination polymer: synthesis, crystal structure, spectroscopy and nano-materials.
Polyhedron, 2014, 81, 147.
132. Madhu Vedichi, S. K. Das
Diverse supramolecular architectures having well-defined void spaces formed from a pseudorotaxane cation: influential role of metal dithiolate
complex anions.
Cryst. Growth Des. 2014, 14, 2343.
131. Bharat Kumar Tripuramallu, Paulami Manna, S. K. Das
Structural library of coordination polymers based on flexible linkers exploiting the role of linker coordination angle: synthesis,
structural characterization and magnetic properties
Cryst Eng. Commun, 2014, 16 4816.
130. Sridevi Yerra, A. Srinivasa Rao and Samar K. Das
Synthesis and structural characterization of Lindqvist type mixed-metal cluster anion [V
2W
4O
19]
4-in discrete and coordination polymer compounds
J. Mol. Struct. 2014, 1062, 53.
129. Paulami Manna, Bharat Kumar Tripuramallu, S. K. Das
Influential role of geometrical disparity of linker and metal ionic radii in elucidating the structural diversity of coordination polymers based
on angular di-carboxylate and bis-pyridyl igands
Cryst. Growth Des. 2014, 14, 278.
2013
128. Kishore Ravada, S. K. Das
Synthesis, structural characterization and properties of new N-heterocyclic carbene Ag(I) complexes
J. Mol. Struct. 2013, 1053, 38.
127. Raju Mekala, Sabbani Supriya, and S. K. Das
Fate of a Giant {Mo
72Fe
30}
-Type Polyoxometalate Cluster in an Aqueous Solution at Higher Temperature: Understanding Related Keplerate
Chemistry, from Molecule to Material,
Inorg. Chem. 2013, 52, 9708.
126. Bharat Kumar Tripuramallu, S. K. Das,
Hydrothermal synthesis and structural characterization of metal organophosphonates oxide materials: role of metal-oxo clusters in the self assembly
of metal phosphonate architectures
Cryst. Growth Des. 2013, 13, 2426.
125. T. Dhanabal, M. Sethuram, G. Amirthaganesan, S. K. Das
Spectral, thermal, structural, optical and antimicrobial activity studies on 2-methylimidazolinium picrate - An organic charge transfer complex
J. Mol. Struct. 2013, 1045, 112.
124. Sridevi Yerra, Sabbani Supriya, S. K. Das
Reversible morphological transition between nano-rods to micro-flowers through micro-hexagonal crystals in a sonochemical synthesis based on a
polyoxovanadate compound
Inorg. Chem.Commun. 2013, 35, 54.
123. Chullikkattil P. Pradeep and S. K. Das
Coordination and Supramolecular Aspects of the Metal Complexes of N-Salicyl-b-amino alcohol Schiff base Ligands: Towards Understanding the
Roles of Weak Interactions in Asymmetric Catalysis
Coord. Chem. Rev. 2013, 57, 1699.
122. T. Dhanabal, G. Amirthaganesan, M. Dhandapani, S. K. Das
Spectral, crystal structure, thermal and antimicrobial characterization of an organic charge transfer complex-3,5- Dimethylpyrrazolinium picrate
J. Mol Struct. 2013, 1035, 483.
121. Kishore, Ravada, S. K. Das
N-Heterocyclic based new nickel-bis(dithiolene) complexes: synthesis, characterization and properties
Polyhedron 2013, 50, 612.
120. Arti Bhujade, S. K. Das, M.B. Patil
Induction of Apoptosis in A431 skin cancer cells by Cissus quandrangularis Linn stem extract by altering Bax/Bcl2 ratio, release of Cytochrome
c from mitochondria and PARP cleavage
RSC- Food & Function 2013, 4, 338.
119. Bharat kumar Tripuramallu, S. K. Das
Influence of Biphenyl Spacer Appended to the Flexible Phosphonate arms in Modulating the Dimensionality of the Coordination Polymers:
Synthesis, Structural Chemistry and Magnetic Properties
J. Solid State Chem., 2013, 197, 499.
118. Ramababu Bolligarla, Samala Nagaprasad Reddy, Gummadi Durgaprasad, Vudagandla Sreenivasulu and S. K. Das
Influence of the substituents on the electronic- and electrochemical- properties of a new square-planar nickel-bis(quinoxaline-6,7-dithiolate)
system: synthesis, spectroscopy, electrochemistry, crystallography and theoretical investigation.
Inorganic Chemistry 2013, 52, 66.
117. T. Dhanabal, G. Amirthaganesan, M. Dhandapani, S. K. Das
Synthesis, structural, thermal and nonlinear optical characterization of benzotriazolinium picrate crystals,
OPTIK 2013, 124, 1966.
2012
116. Bharat kumar Tripuramallu, Sandip Mukherjee , S. K. Das
Mechanistic aspects for the formation of copper dimer bridged by phosphonic acid and extending its dimensionality by organic and
inorganic linkers: synthesis, structural characterization, magnetic properties and theoretical studies
Cryst. Growth Des. 2012, 12, 5579.
115. T. Dhanabal, G. Amirthaganesan, M. Dhandapani, S. K. Das
Journal of molecular crystals and Liquid crystals, 2012, 569, 112.
114. T. Dhanabal, G. Amirthaganesan, M. Dhandapani, S. K. Das
Journal of Chemical Sciences, 2012 ,124, 951.
113. Paulami Manna, Bharat Kumar Tripuramallu, S. K. Das
Synthesis, Structural Characterization and Magnetic Properties of a New Series of Coordination Polymers: Importance of Steric Hindrance
at the Coordination Sphere
Cryst. Growth Des. 2012, 12, 4607.
112. Gummadi Durgaprasad, S. K. Das
1,2-Ene dithiolate bridged diiron carbonyl-phosphine and -Phosphite Complexes in relevance to the active site of [FeFe]-hydrogenases:
synthesis, characterization and electrocatalysis
Journal of Organometallic Chemistry, 2012,717, 29.
111. Kishore, Ravada, S. K. Das
Diversities of Coordination Geometry Around the Cu
2+ Center in Bis(maleonitriledithiolato)metalate Complex Anions: Geometry Controlled
by Varying the Alkyl Chain Length of Imidazolium Cations
Cryst. Growth Des. 2012, 12, 3684.
110. Arti M. Bhujade, Suhas Talmale, Naresh Kumar, Geetika Gupta, P. Reddanna, S. K. Das, M.B. Patil
Evaluation of Cissus quadrangularis extracts as an inhibitor of COX, 5-LOX and Proinflammatory Mediators
Journal of Ethnopharmacology, 2012 ,141, 989.
109. Ramababu Bolligarla, S. K. Das
Sulphur Oxygenation of [Ni(btdt)
2]
2� by Aerial Oxidation at Ambient Conditions: Syntheses, Crystal structures and Properties of
[Bu
4N]
2[Ni(btdt)
2] and [Bu
4N]
2[Ni(btdtO
2)
2].H
2O ({btdt}
2-=2,1,3-Benzenethiadiazole-5,6-dithiolate)
Eur. J. Inorg.Chem. 2012, 17, 2933.
108. Monima Sarma, Tanmay Chatterjee, S. K. Das
Ammonium Crown Ether Based Host Guest Systems: N-H...O Hydrogen Bond Directed Guest Inclusion Featuring N-H Donor Functionalities in
Angular Geometry.
RSC Advances, 2012, 2, 3920.
107. Gummadi Durgaprasad, Ramababu Bolligarla, S. K. Das
Synthesis, crystal structure and electrocatalysis of 1,2-ene dithiolate bridged diiron carbonyl complexes in relevance to the active site of
[FeFe]-hydrogenases
Journal of Organometallic Chemistry, 2012, 706, 37.
106. Monima Sarma, Tanmay Chatterjee, Susanta Ghanta, S. K. Das
D-pi-A-A-pi-D Prototype 2,2'-Bipyridine Dyads Exhibiting Large Structure and Environment Sensitive Fluorescence: Synthesis, Photophysics and
Computation
J. Org. Chem. 2012, 77, 432
105. Monima Sarma, Tanmay Chatterjee, Hanumanthugari Vindhya S. K. Das
Spontaneous Resolution through Helical Association of a Cu-azamacrocyclic Complex with Lindqvist-type Isopolyanion
Dalton Trans. 2012, 41, 1862.
104.Bharat Kumar Tripuramallu, Paulami Manna, Samala Nagaprasad Reddy, S. K. Das
Factors affecting the conformational modulation of flexible ligands in the self assembly process of coordination polymers: synthesis,
structural characterization, magnetic properties and theoretical studies of [Co(pda)(bix)]
n, [Ni(pda)(bix)(H
2O)]
n, [Cu(pda)(bix)
2(H
2O)
2]
n.8nH
2O,
[Co
2(μ-OH)(pda)(ptz)]
n.nH
2O, [Co(hfipbb)(bix)
0.5]
n and [Co(2,6-pydc)(bix)
1.5]
n 4nH
2O
Cryst. Growth Des. 2012, 12, 777.
2011
103. V. Madhu and S. K. Das
Neutral Coordination Polymers Based on a Metal-Mono(dithiolene) complex: Synthesis, Crystal Structure and Supramolecular Chemistry of
[Zn(dmit)(4,4′-bpy)]
n, [Zn(dmit)(4,4′-bpe)]
n and [Zn(dmit)(bix)]
n (4,4′-bpy = 4,4′-bipyridine, 4,4′-bpe = trans-1,2-Bis(4-pyridyl)ethene,
sbix = 1,4-bis(imidazole-1-ylmethyl)-benzene,
Dalton Trans., 2011, 40 (48), 12901.
102. Tanmay Chatterjee, Monima Sarma, Susanta Ghanta, S. K. Das
Sterically driven electronic properties of naphthalene and anthracene end capped 2,2'-bipyridine luminophores: synthesis and density
functional theory,
Tet. Lett. 2011 , 52, 5460.
101. Monima Sarma, Tanmay Chatterjee, S. K. Das
Inorganic-organic hybrid materials based on Co(III) tetra-aza-macrocycle complexes and Lindqvist type poly-oxo anions: synthesis,
characterization and spectroscopy of [CoIII(L)(NO
2)
2]
2[Mo
6O
19] and [CoIII(L)(NCS)
2]
2[W
6O
19] .2CH
3CN (L = Transdiene),
J. Mol. struc. 2011, 104, 31.
100. Ramababu Bolligarla, Bharat Kumar Tripuramallu, Vudagandla Sreenivasulu and S. K. Das
Synthesis and structural characterization of potassium coordination polymers based on a copper-bis(dithiolato) complex [Cu(btdt)
2]
-
({btdt}2- = 2,1,3-benzenethiadiazole-5,6-dithiolate): role of coordinating solvents and counter cation,
Indian Journal of Chemistry Sec. A 2011, 50A, 1410.
99. Ramababu Bolligarla, G. Durgaprasad and S. K. Das
6,7,6',7'-Tetraphenyl-[2,2']bi[1,3-dithia-5,8-diaza-cyclopenta[b]napthalenylidene]
Acta crystallography Section E, 2011, E67, O2231.
98. G. Durgaprasad .Ramababu Bolligarla, and S. K. Das
Synthesis, structural characterization and electrochemical studies of [Fe
2(L)(CO)
6] and [Fe
2(L)(CO)
5(PPh
3)]
(L = pyrazine-2,3-dithiolate, quinoxaline-2,3-dithiolate and pyrido[2,3-b]pyrazine-2,3-dithiolate): towards modeling the active site of
[FeFe]-Hydrogenase
Journal of Organometallic Chemistry, 2011, 696, 3097.
97. Ramababu Bolligarla, S. K. Das
New Square-Planar Bis(Dithiolene) Complexes: Synthesis, Crystallography and Properties of [Bu
4N][MIII(btdt)
2] (M = Cu, Au) and [Bu
4N]
2[PtII(btdt)
2]
({btdt}
2- = 2,1,3-Benzenethiadiazole-5,6-dithiolate)
Aust. J. Chem. 2011, 64, 550.
96. Ramababu Bolligarla, S. K. Das
Synthesis of new intramolecular charge transfer A-D-A tetrathiafulvalene-fused triads exhibiting large solvent sensitive emission behavior
Tet. Lett. 2011, 52, 2496.
95. Ramababu Bolligarla, G. Durgaprasad and S. K. Das
Synthesis, molecular structure and supramolecular chemistry of a new nickel-quinoxaline dithiolate system [Bu
4N]
2[Ni(6,7-qdt)
2]
(6,7-qdt = quinoxaline-6,7-dithiolate) and comparison of its electronic and electrochemical
properties with those of
[Bu
4N]
2[Ni(qdt)
2] (qdt = quinoxaline-2,3-dithiolate)
Inorg. Chem. Commun. 2011, 14, 809.
94. A. Srinivasa Rao, Upama Baruah, S. K. Das
Stabilization of [BiCl
6]
3- and [Bi
2C
l10]
4- with Various Organic Precursors as Cations Leading to Inorganic-Organic Supramolecular
Adducts: Syntheses, Crystal Structures and Properties of [C
5H
7N
2]
3[BiCl
6], [C
5H
7N
2][C
5H
8N
2][BiCl
6] and [C
10H
10N
2]
2[Bi
2C
l1O]
Inorganic Chimica Acta. 2011, 372, 206.
93. Kishore Ravada, Bharat Kumar Tripuramallu, Gummadi Durgaprasad and S.K. Das
Ion-pair charge transfer complex with near-IR absorption: Synthesis, crystal structure and properties of [Hb]
2[Cu(mnt)
2]
(Hb = 1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazol-3-ium)
J. Mol. struc. 2011, 990, 37.
92. Bharat Kumar Tripuramallu, Kishore Ravada and S.K. Das
Understanding the Formation of Metal-oxide Based Inorganic Solids: Assessing the
Influence of Tetrazole Molecule.
Inorganic Chimica Acta. 2011, 368, 132.
91. Monima Sarma, Tanmay Chatterjee, S. K. Das
Bringing an important macrocycle into polyoxometalate matrix: synthesis, crystal structure, spectroscopy and electrochemistry of
[Co
III(transdiene)(Cl)
2]
2[Mo
6O
19], [Ni
II(transdiene)][W
6O
19] DMSO.DCM and [Zn
II(transdiene)(Cl)]
2[W
6O
19].
Dalton trans. 2011, 40, 2954.
90. A. Srinivasa Rao, T. Arumuganathan, V. Shivaiah, S. K. Das
Polyoxometalates: toward new materials
Journal of Chemical Sciences (Bangalore). 2011, 123, 229.
89. S. Supriya and S. K. Das
Solid to solid formation at the solid-liquid interface leading to a chiral coordination polymer from an achiral monomer
Chem. Comm. 2011, 47, 2062.
2010
88. Tanmay Chatterjee, Monima Sarma and S. K. Das
Donor-acceptor amphiphilic 2,2'-bipyridine chromophores: synthesis, linear optical and thermal properties
Tet. Lett. 2010, 51 6906-6910.
87.T. Arumuganathan, S. K. Das
Exploiting the linking propensity of a water encapsulated POV cluster anion [As
6V
15O
42(H
2O)]
6 towards lanthanide cations: syntheses,
crystal structures and thermal properties of [{M(H
2O)
7}
2(As
6V
15O
42(H
2O)].xH
2O
( M = La
3+, Sm
3+ and Ce
3+; x = 12, 13 and 11 respectively)
Inorganic Chimica Acta 2010 363, 4374-4380.
86. T. Arumuganathan, A. Srinivasa Rao and S. K. Das
Polyoxometalate Supported Transition Metal Complexes: Synthesis, Crystal Structures and Supramolecular Chemistry
Cryst. Growth Des. 2010, 10, 4272-4284.
85. Bharat Kumar Tripuramallu, Kishore Ravada and S.K. Das
Synthesis, structural characterization and properties of one-dimensional coordination polymers of cobalt (II)- and nickel(II)-phosphonate
complexes with 2, 2-bipyridine as a secondary ligand component: observation of both
cis- and trans-conformations of a diphosphonic acid
Polyhedron, 2010, 29, 2985.
84. S. Supriya and S. K. Das
A simple coordination complex exhibits color change on slight structural modification: synthesis and crystal structures of violet and yellow
forms of [Ni
II(opda)
2(NCS)
2] (opda = orthophenylenediamine)
Journal of Chemical Sciences (Bangalore), 2010, 122, 731
83. Tanmay Chatterjee, Monima Sarma and S. K. Das
Polyoxometalate associated ion-pair solid based on a crown ether inclusion complex: synthesis, structure and spectroscopy
Journal of Molecular structure, 981 (2010) 34-39.
82. A. Srinivasa Rao, Bharat Kumar Tripuramallu, Kishore Ravada and S.K. Das
2-Aminoanilinium 2-Chloroacetate
Acta crystallography Section E, 2010, E-66, o1945.
81. Monima Sarma, Tanmay Chatterjee, S. K. Das
A copper-cyclen coordination complex associated with a polyoxometalate anion: synthesis, crystal structure and electrochemistry of
[Cu (cyclen)(MeCN)][W
6O
19]
Inorg. Chem. Commun, 2010, 13,1114.
80. Ramababu Bolligarla and S. K. Das
Dimensionality of coordination polymers decided by the type of hybridization of the central carbon atom of the solvent molecule that
coordinates to an alkali metal cation: from discrete to 3-D networks based on a
gold(III) bis(dithiolene) complex
Cryst. Eng. Comm. 2010, 12, 3409-3412
79.Tanmay Chatterjee, Monima Sarma and S. K. Das
Supramolecular Architectures from Ammonium-Crown Ether Inclusion Complexes in Polyoxometalate Association: Synthesis, Structure and
Spectroscopy
Cryst. Growth Des. 2010, 10, 3149.
78. Ramababu Bolligarla, Ravada Kishore, Gummadi Durgaprasad and Samar K. Das*
Acid-base behavior of a simple metal bis(dithiolate) system: synthesis, crystal structure and spectroscopy of [Bu
4N]
2[M
II(ppdt)
2]
(M = Ni, Pt; ppdt = pyrido[2,3-b]pyrazine-2,3-dithiolate)
Inorganic Chimica Acta 2010 , 363, 3063
77. A Srinivasa Rao, Eadi Sunil Babu, K C Kumar Swamy* and S. K. Das*.
Isolation and structural characterization of 1, 5-benzodiazepinium cation in an Inorganic-organic hybrid compound [C12H17N2]3[Bi2Cl9].2EtOH
Polyhedron, 2010, 29, 1706-1714
76. Tanmay Chatterjee, Monima Sarma and S. K. Das
Synthesis and photo-physical properties of methoxy substituted π-sonjugated-2,2'-bipyridines
Tet. Lett. 2010, 51, 1985-1988.
2009
75. P. Jhansi Lakshmi, B. V. S. Suneel Kumar, Ravi Shasi Nayana, M. Srinivas Mohan, Ramababu Bolligarla, S. K. Das, M. Uday Bhanu,
Anand K. Kondapi, Muttineni Ravikumar*
Design, synthesis, and discovery of novel non-peptide inhibitor of Caspase-3 using
ligand based and structure based virtual screening approach
Bioorganic & Medicinal Chemistry 2009, 17, 6040-6047.
74. R. Bolligarla, G. Durgaprasad and S. K. Das*
A nitrogen rich Ni(II)-dithiolate system exhibiting acid-base behavior: synthesis, supramolecular structure and spectroscopy of
[Bu
4N]
2[Ni
II(ppdt)
2](ppdt = pyrido[2,3-b]pyrazine-2,3-dithiolate)
Inorg. Chem. Commun 12 (2009) 355-358
73.S. Supriya and S. K. Das*
Reversible nitro-nitrito inter-conversion in a simple mono-nuclear nickel(II) complex [Ni
II{C
6H
4(NH
2)
2}
2(NO
2)
2] in the solid state,
2009 Inorg. Chem. Commun.
72. A Srinivasa Rao, Abhijit Pal , Samar K Das , Rajarshi Ghosh
Chiral synthesis of a mononuclear Nickel(II) complex from an Achiral Tripodal amine ligand: Spontaneous resolution
Inorg.Chem .2009 , 48, 1802-1804.
71. C. P. Pradeep and Samar K. Das
Chiral supramolecular metal-organic architectures from dinuclear copper complexes
Polyhedron 2009,28, 630-636
70. T. Arumuganathan and Samar K. Das
Discrete Polyoxovanadate cluster into an Organic Free Metal-Oxide Based Material: Syntheses, Crystal Structures and Magnetic Properties
of a New Series of Lanthanide Linked-POV Compounds [{Ln(H
2O)
6}2As
8V
14O
42(SO
3)] 8H
2O
(Ln = La
3+, Sm
3+ and Ce
3+)
Inorg. Chem. 2009,48 ,496-507
69. Samar K. Das*
Book Chapter: Supramolecular Structures and Polyoxometalates in Macromolecules Containing Metal and Metal-Like Elements: Supramolecular
and Self-Assembled Metal Containing Materials
(Eds. A. S. Abd-El- Aziz, C. E. Carraher, Jr., C. U. Pittman, Jr., M. Zeldin),
John Wiley & Sons, Inc, Hoboken, New Jersey, USA, Volume 9, Chapter 3, pp. 61-123
2008 - 1992
68. T. Arumuganathan, A. Srinivasa Rao and Samar K. Das
Non-covalent O⋅⋅⋅O interactions among isopolyanions using a cis- {MoO
2} moiety by the assistance of N-H⋅⋅⋅O hydrogen bonds
J. Chem. Sci., 2008, 120, 297-304.
67. V. Shivaiah, T. Chatterjee, and Samar K. Das
Stabilization of a New Type of Water - Octamer in the Crystalline Hydrate of an Inorganic - Organic Hybrid Material : Synthesis and
Characterisation of [{Cu (Phen) (H
2O)
2}
2 (Mo
8O
26) ].8 H
2O
Synthesis and Reactivity in Inorganic, Metal-Organic & Nano-Metal Chemistry, 2008, 38, 12
66. V. Madhu and S. K. Das*
A New Series of Asymmetrically Substituted Bis(1,2-dithiolato)nickel(III) Complexes
Exhibiting Near IR Absorption and Structural Diversity
Inorg. Chem. 2008, 47, 5055
65. T. Arumuganathan, A. Srinivasarao, T. Vijay Kumar and S. K. Das*
Two different Zinc(II)-aqua complexes held up by a metal-oxide based support: Synthesis, crystal structure and catalytic activity of
[HMTAH]
2[{Zn(H
2O)
5}{Zn(H
2O)
4}{Mo
7O
24}]∙2H
2O (HMTAH = protonated hexamethylenetetramine)
Journal of Chemical Sciences 2008, 120, 95-103.
64. C. P. Pradeep, P. S. Zacharias and S. K. Das*
Identification of ONO...ONO interactions among inorganic coordination complex molecules in the crystal lattice of a chiral Mn(IV) compound
Inorg. Chem. Commun. 2008, 11, 89-93.
63. C. P. Pradeep, P. S. Zacharias and S. K. Das*
Enantiopure Mono- and Mixed Valent Multi-nuclear Cobalt Complexes from Amino Alcohol Based Ligands: How Substitution on a Ligand Controls
Nuclearity in an Identical Reaction Condition of Chiral Complex Synthesis
Eur. J. Inorg. Chem. 2007, 5377-5389.
62. S. Supriya and Samar K. Das
Reversible Single Crystal to Single Transformation Through Fe-O(H)Me/Fe-OH
2 Bond Formation/Bond Breaking In a Gas-Solid Reaction at an
Ambient Condition
J. Am. Chem. Soc., 2007, 129, 3464 - 3465
61. V. Shivaiah, T. Chatterjee, K. Srinivasu and Samar K. Das
A water pipe held up by a polyoxometalate supported transition metal complex: synthesis and characterization of
[Cu
2(phen)
2(CH
3COO)(CH
3COOH)(H
2O)
2][Al(OH)
6Mo
6O
18].28H
2O
Eur. J. Inorg. Chem., 2007, 231 - 234 (Featured on the cover page of January, 2007, 2nd Issue)
60. V. Madhu and Samar K. Das
One pot synthesis of a Mn(III)-Cu(II)-Mn(III) trinuclear heterometallic compound formed by Mn...S-Cu-S...Mn supramolecular interactions:
crystal structure of [{Mn
III(salph)(H
2O)}
2{Cu
II(mnt)
2}].4DMF
J. Chem. Sci., 2006, 118, 611 - 617
59. V. Madhu and Samar K. Das
A New Approach to Functionalize an Organic Compound Through the Influence of Metal-bis(Dithiolene) Complexes Leading to Ion-Pair Compounds
Exibiting Strong Emission at Room Temperature in the Visible Region
Inorg. Chem., 2006, 45, 10037 - 10039
58. C. P. Pradeep, P. S. Zacharias and Samar K. Das
A Chiral Mn (IV) Complex And It's Supramolecular Assembly: Synthesis, Characterization and Properties
J. Chem. Sci., 2006, 118, 311 - 317
57. C. P. Pradeep, S. Supriya, P. S. Zacharias and Samar K. Das
A tetranuclear Copper (II) complex stabilizes an extended structure of a water nonamer: synthesis and characterization of
[Cu
4(C
54H
46N
4O
14)(OH)
2].10 H
2O
Polyhedron, 2006, 25, 3588 - 3592
56. C. P. Pradeep, P. S. Zacharias and Samar K. Das
Synthesis and structural characterization of a carboxylate bridged tetranuclear copper complex derived from reduced Schiff base asymmetric
compartmental ligand containing an amino acid side arm
Inorg. Chem. Commun., 2006, 9,  1071 - 1074  DOI:10.1016/j.inoche.2006.06.019
55. M. Prabhakar, P. S. Zacharias and Samar K. Das
Water-Chloride interactions: Left- and Right- handed aquo-chloro supramolecular helices anchored by a chiral schiff base nickel complex
Inorg. Chem. Commun., 2006, 9, 899 - 902  DOI:10.1016/j.inoche.2006.05.010
54. P. Raghavaiah, S. Supriya and Samar K. Das
Sulfate anion helices formed by the assistance of a flip-flop water chain
Chem. Commun., 2006, 2762 - 2764; DOI: 10.1039/B605899J
53. V. Madhu and Samar K. Das
N-H----S Hydrogen Bonds in a New Family of Ion-Pair Complexes Between Cationic Nickel Tetraazabicyclononane and Anionic Metal Dithiolates:
Synthesis, Characterization and Properties of [Ni(C
9H
22N
6)][M(mnt)
2] (M(II) = Cu, Ni, Pd)
Eur. J. Inorg. Chem., 2006, 1505-1514
52. V. Shivaiah and Samar K. Das
Fivefold Coordination in Cu(II) Aqua Ion: A Supramolecular Sandwich Consisting of Two Crown Ethers and a Trigonal Bipyramidal [Cu(H
2O)
5]
2+ Ion
Angew. Chem. Int. Ed., 2006, 45, 245-248
51. V. Shivaiah and Samar K. Das
Polyoxometalate Supported Transiotion Metal Complexes and Their Charge Complementarity: Synthesis and Characterization of
[M(OH)
6Mo
6O
18{Cu(phen)(H
2O)
2][M(OH)
6Mo
6O
18{Cu(phen)(H
2O)Cl}
2].5H
2O) (M=Al
3+, Cr
3+)
Inorg. Chem., 2005, 44, 8846 - 8854.
50. V. Shivaiah and Samar K. Das
Inclusion of a Cu
2+ Ion by a Large Cavity Crown Ether Dibenzo-24-Crown-8 Through Supramolecular Interactions
Inorg. Chem., 2005, 44, 7313 - 7315
49. V. Madhu and Samar K. Das
Supramolecular p-p assembly of a neutral [Cu(salen)] complex via the templating effect of an ionic inorganic complex Na
2[Cu(mnt)
2] forming a
framework type material having well-defined channels
Inorg. Chem. Commun., 2005, 8, 1097 - 1100
48. Chullikkattil P. Pradeep, Panthapally S. Zacharias, and Samar K. Das
A Chiral Copper Complex Leads to Supramolecular Homochiral Helices via O-H---Cl-Cu Interactions
Eur. J. Inorg Chem., 2005, 3405 - 3408
47. C. P. Pradeep, P. S. Zacharias and S. K. Das
Synthesis, structural characterization and properties of an optically active mononuclear Mn(IV) complex
Polyhedron,. 2005, 24, 1410 - 1416.
46. V Shivaiah and S. K. Das
Supramolecular assembly based on a heteropolyanion: synthesis and crystal structure of Na
3(H
2O)
6[Al(OH)
6Mo
6O
18] . 2H
2O
J. Chem. Sci.,2005, 117, 227 - 233.(Got cover page of this issue)
45. M. Prabhakar, P. S. Zacharias and S. K. Das
Self-assembly of a Fluorescent Chiral Zinc(II) Complex that Leads to Supramolecular Helices
Inorg. Chem., 2005, 44, 2585 - 2587.(Came within top accessed articles)
44. C. P. Pradeep, P. S. Zacharias, S. K. Das
Synthesis and characterization of a chiral dimeric copper(II) complex: crystal structure of [Cu
2(m-Cl)
2(HL)
2] . H
2O
(H
2L = S-(-)-2-[(2-hydroxy-1-phenyl-ethylimino)-methyl-phenol)
J. Chem. Sci., 2005, 117, 133 - 137.
43. P. Raghavaiah, S. Supriya and S. K. Das
Hydrogen bonded Supramolecular network in a simple organic-inorganic salt: hydrophilic gallery formed between two hydrophobic layers in
the crystal structure of [C
6H
9N
2]ClO
4.H
2O
CrystEngComm., 2005, 7, 167 - 170. DOI: 10.1039/b500170f (Came within top 10 accessed articles)
42. Sabbani Supriya, K. Swarna Latha, and Samar K. Das
A New Type of Supramolecular Assembly via Hydrogen Bond Templating: Identification of Rare Monodentate Acetate Coordination in
[Fe
3(μ
3-O)(μ
2-CH
3COO)
6(H
2O)
2(CH
3COO)]TClO
4 (T = 2,6-Diaminopyridinium Cation,
C
5H
8N
3 and 2-Aminopyridinium Cation, C
5H
7N
2)
Eur. J. Inorg. Chem., 2005, 357 - 363. DOI: 10.1002/ejic.200400370
41. A. Muller, B. Botar, S. K. Das, H. B�gge, M. Schmidtmann and A. Merca
On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information
about the unique formation
Polyhedron, 2004, 23, 2381 - 2385.
40. C. P. Pradeep, T. Htwe, P. S. Zacharias and S. K. Das
First structurally characterized optically active mononuclear Mn(IV) complex: synthesis, crystal structure and properties of [Mn
IVL
2]
(H
2L = S-(-)-2-[(2-hydroxy-1-phenyl-ethylimino)-methyl]-phenol)
New J. Chem., 2004, 28, 735 - 739. DOI: 10.1039/b315658c
39. V. Madhu , S. K. Das
Near-IR absorption due to supramolecular electronic interaction in an extended 3D hydrogen-bonding network material; synthesis, crystal
structure and properties of [4,4'-H
2bpy][Cu(mnt)
2]
Polyhedron, 2004, 23, 1235 - 1242.
38. V. Shivaiah, T. Arumuganathan, S. K. Das
Chirality of a Strandberg-type heteropolyanion, [S
2Mo
5O
23]
4-
Inorg.Chem.Commun., 2004, 7, 367 - 369.
37. B. R. Srinivasan, S. C. Sawant, and S. K. Das
More insight into the crystal structure of [Co(H
2O)
4(4-nba)
2].2H
2O (4-nba=para-nitrobenzoate): An unprecedented hydrogen bonded
Supramolecular network
Indian J. Chem., 2004, 43A, 1066 - 1075.
36. A. Muller, S. K. Das, E. Krickemeyer, and C. Kuhlmann
Polyoxometalate Clusters: Giant Wheels and Balls
Inorg. Synth., 2004, 34, 191 - 200.
35. P. K. Chaudhury, K. Nagarajan, A. Kumar, R. Maiti, S. K. Das and S. Sarkar
Redox reaction between [Bu
4N]
2[Mo
VIO
2(mnt)
2] and thiophenol in relevance to the autoreduction in the crystallization process of oxidized
form of sulfite oxidase
Indian J. Chem., 2003, 42A, 2223 - 27.
34. A. Muller, S. K. Das, S. Talismanov, S. Roy, E. Beckmann, H. Bgge, M. Schmidtmann, A. Merca, A. Berkle, L. Allouche, Y. Zhou and L. Zhang
Trapping Cations in Specific Positions in Tuneable "Artificial Cell" Channels: New Nanochemistry Perspectives
Angew. Chem. Int. Ed. Engl., 2003, 42, 5039 - 5044.
33. V.Shivaiah, M.Nagaraju, and S. K. Das
Formation of a spiral-shaped Inorganic-Organic hybrid Chain [Cu
II(2,2'-bipy)(H
2O)
2Al(OH)
6Mo
6O
18]
n1
n- : Influence of Intra- and Inter-Chain
Supramolecular Interactions
Inorg.Chem., 2003, 42, 6604 - 6606. DOI: 10.1021/ic034581f
32. S. Supriya, and S.K. Das
Small water clusters in crystalline hydrates
J. Cluster Sci., 2003, 14, 337-66.
31. S. Supriya and S. K. Das
A cyclic (H
2O)
4 cluster characterized in the solid state disappears on heating and regenerates from water vapor: a supramolecular
reversible gas-solid reaction
New J. Chem., 2003, 27, 1568 - 74. DOI: 10.1039/b303539p
30. S . Supriya, S. Manikumari, P. Raghavaiah, and S. K. Das
A Cyclic Supramolecular (H
2O)
4 Cluster in the Solid State and its Reversible Formation from Water Vapor in s Gas-Solid Phase Reaction
New J.Chem., 2003, 27, 218 - 220. DOI: 10.1039/b205695j
29. S. Supriya and S. K. Das
A Simple Cu(II) Complex, [Cu
II{C
6H
4(NH
2)
2}
2(NO
3)
2] with an Unprecedented Hydrogen Bonding Supramolecular Network in the Solid State and Its
Solution Emission at Room Temperature in the Visible Region
Inorg. Chem. Commun., 2003, 6, 10 - 14.
28. S. Manikumari,V.Shivaiah and S. K. Das
Identification of a Near-Linear Supramolecular (H
2O)
2 Cluster in the Solid State
Inorg. Chem., 2002, 41, 6953 - 6955. DOI: 10.1021/ic025803x
27. V. Shivaiah, S. Hajeebu, and S. K. Das
The first one-dimensional heteropoly tungstovanadate coordination polymer: [(V
VO
4)W
VI8V
IV4O
36(V
IVO)
2]
n7n-
Inorg. Chem. Commun., 2002, 5, 996.
26. V. Shivaiah, P. V. Narasimha Reddy, L. Cronin, and S. K. Das
A Novel Polyoxometalate Chain Formed from Heteropolyanion Building Blocks and Lanthanum Cation Linkers: [La(H
2O)7Al(OH)
6Mo
6O
18]
n 4nH
2O
J. Chem. Soc. Dalton Trans., 2002, 3781 - 3782. DOI: 10.1039/b207149e (Got cover page of this Issue)
25. V. Shivaiah and S. K. Das
Synthesis and Characterization of a Reduced Heteropoly tungsto vanadate: (NH
4)
7[V
VO
4W
VI10V
IV2O
36] ca. 22 H
2O
Proc. Indian Acad. Sci., Chem. Sci., 2002, 114, 107- 114.
24. A. Muller, S. K. Das, M. O. Talismanova, H. Bgge, P. Kgerler, M. Schmidtmann, S. S. Talismanova, M. Luban, and E. Krickmeyer
Paramagnetic Keplerate "Necklaces" Synthesized by a Novel Room-Temperature Solid-State Reaction
Angew. Chem. Int. Ed. Engl., 2002, 41, 579 - 582.
23. A. Muller, S. K. Das, C. Kuhlmann, H. Bgge, M. Schmidtmann, E. Diemann, E. Krickemeyer, J. Hormes, H. Modrow, and M. Schindler
On the Option of Generating Novel Type Surfaces with Multiphilic Ligands within the Cavity of a Giant Metal-Oxide Based Wheel Type Cluster:
Chemical Reactions with Well-Defined Nanoobjects
Chem. Commun., 2001, 655 - 656.
22. A. Muller, S. K. Das, H. Bgge, M. Schmidtmann, A. Botar, and A. Patrut
Generation of Cluster Capsules (I
h) from Decomposition Products of a Smaller Cluster (Keggin-T
d) While Surviving Ones Get Encapsulated:
Species with Core Shell Topology Formed by a Fundamental Symmetry-Driven Reaction
Chem. Commun., 2001, 657 - 658.
21. A. Muller, R. Maiti, M. Schmidtmann, H. Bgge, S. K. Das, and W. Zhang
Mimicking Oxide Surfaces: Different Types of Defects and Ligand Coordination at Well Defined Positions of a Molybdenum Oxide Based Nanocluster
Chem. Commun., 2001, 2126 - 2127.
20. A. Muller, S. K. Das, E. Krickemeyer, P. Kgerler,H. Bgge, and M. Schmidtmann
Cross- linking Nanostructured Spherical Capsules as Building Units by Crystal Engineering: Related Chemistry
Solid State Sciences, 2000, 2, 847 - 854.
19. A. Muller, S. K. Das, P. Kgerler, H. Bgge, M. Schmidtmann, A. X. Trautwein, V. Schnemann, E. Krickemeyer, and W. Preetz
A New Type of Supramolecular Compound:Molybdenum- Oxide-Based Composites Consisting of Magnetic Nanocapsules with Encapsulated Keggin-
Ion Electron Reservoirs Cross-Linked to a Two-Dimensional Network
Angew. Chem. Int. Ed. Engl., 2000, 39, 3413 - 3417.
18. A. Muller, E. Krickemeyer, S. K. Das, P. Kgerler, S. Sarkar, H. Bgge, M. Schmidtmann, and S. Sarkar
Linking Icosahedral, Strong Molecular Magnets {Mo
VI72Fe
III30} to layers: a Solid State Reaction at Room Temperature
Angew. Chem. Int. Ed. Engl., 2000, 39, 1612 - 1615.
17. A. Muller, C. Beugholt, M. Koop, S. K. Das, M. Schmidtmann, and H. Bgge
Facile Synthesis and Structure of Crystalline Molybdenum Blue Compounds including one with a High Degree of Defects:
Na
26[Mo
142O
432(H
2O)
58H
14]ca.300 H
2O and
Na
16[(MoO
3)
176(H
2O)
63(CH
3OH)17H
16]ca.600 H
2O 6 CH
3OH
Z. Anorg. Allg. Chem., 1999, 625, 1960 - 1962.
16. A. Muller, S. Polarz, S. K. Das, E. Krickemeyer, H. Bgge, M. Schmidtmann, and B. Hauptfleisch
'Open and Shut' for Guests in Molybdenum-Oxide-Based Giant Spheres, Baskets, and Rings ThatContain the Pentagon as a Common Structural Element
Angew. Chem. Int. Ed. Engl., 1999, 38, 3241 - 3245.
15. A. Muller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bgge, M. Schmidtmann, and B. Hauptfleisch
Rapid and Simple Isolation of the Crystalline Molybdenum- Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions:
Na
15[Mo
VI126Mo
V28O
462H
14(H
2O)
70]
0.5 [Mo
VI124Mo
V28O
457H
14(H
2O)
68]
0.5 ca. 400 H
2O and
Na22[MoVI118MoV28O442 H14(H2O) 59] ca. 250 H2O
Z. Anorg. Allg. Chem., 1999, 625, 1187 - 1192.
14. A. Muller, S. K. Das, H. Bgge, C. Beugholt, and M. Schmidtmann
Assembling Nanosized Ring-Shaped Synthons to an Anionic Layer Structure Based on the Synergetically Induced Functional Complementarity
of their Surface-sites: Na
21[Mo
VI126Mo
V28O
462H
14(H
2O)
54(H
2PO
2)
7].H
2O (x 300)
Chem. Commun., 1999, 1035 - 1036.
13. A. Muller, E. Krickemeyer, H. Bgge, M. A. Schmidtmann, C. Beugholt, S. K. Das, and F. Peters
Giant Ring-Shaped Building Blocks Linked to form a Layered Cluster Network with Nanosized Channels:
[Mo
VI124Mo
V28O
429(μ
3-O)
28H
14(H
2O)
66.5]
16-
Chem. Eur. J., 1999, 5, 1496 - 1502.
12. S. K. Das and P. K. Dutta
Intrazeolitic Photoreactions of Ru(bpy)
33+ with Methylviologen
Langmuir, 1998, 14, 5121 - 5126.
11. S. K. Das and P. K. Dutta
Synthesis and Characterization of a Ruthenium Oxide-Zeolite Y Catalyst for Photochemical Oxidation of Water to Dioxygen
Microporous and Mesoporous Materials, 1998, 22, 475 - 483.
10. P. K. Dutta and S. K. Das
Oxidizing Properties of Zeolite Encapsulated Oxobis(2,2'-bipyridine) ruthenium(IV) Complexes Formed by Air Oxidation of
Bis(2,2'-bipyridine)aquaruthenium(II)
J. Am. Chem. Soc., 1997, 119, 4311 - 4312.
9. A. Kumar Jr., S. K. Das, and A. Kumar
Formation of Phenol from Benzene Catalyzed by Polymer Bound Vanadyl Acetylacetonate
J. Catal., 1997, 166, 108 - 110.
8. J. Yadav, S. K. Das and S. Sarkar
A Functional Mimic of the New Class of Tungstoenzyme Acetylene Hydratase
J. Am. Chem. Soc., 1997, 119, 4315 - 4316.
7. S. K. Das, D. Biswas, R. Maiti and S. Sarkar
Modeling the Tungsten Sites of Inactive and Active Hyperthermophilic Pyrococcus furiosus Aldehyde Ferredoxin Oxidoreductase
J. Am. Chem. Soc., 1996, 118, 1387 - 1397.
6. P. K. Chaudhury, S. K. Das and S. Sarkar
Inhibition Patterns of a Model Complex Mimicking the Reductive Half Reaction of Sulfite Oxidase
Biochem. J., 1996, 319, 953 - 959.
5. S. K. Das, A. Kumar Jr., S. Nandrajog and A. Kumar
Polymer Supported VO
2+ Schiff Base Catalyst for Hydroxylation of Benzene;
Tetrahedron Lett., 1995, 7909 - 7912.
4. S. Sarkar, R. Sah, P. K. Chaudhury, R. Maiti and S. K. Das
Stepwise Reduction of Electron-precise, Six- electron, Triangular, [Mo
3S
4(CN)
9]
5- to Electron-rich Seven, Eight and Unstable
Nine-electron Species Resulting in Core Expansion to Electron-precise, Twelve electron
Tetrahedral, [Mo
4S
4(CN)
12]
8-,
Proc. Indian Acad. Sci., Chem. Sci., 1995, 107, 355 - 360.
3. S. K. Das, P. K. Chaudhury, D. Biswas and S. Sarkar
Modeling for the Active Site of Sulfite Oxidase: Synthesis, Characterization, and Reactivity of [Mo
VIO
2(mnt)
2]
2-
(mnt
2- = 1,2-Dicyanoethylenedithiolate)
J. Am. Chem. Soc., 1994, 116, 9061 - 9070.
2. S. Sarkar and S. K. Das
Carbon Dioxide Fixation by [W
IVO(mnt)
2]
2-: Functional Model for the Tungsten Formate Dehydrogenase of Clostridium thermoaceticum
Proc. Indian Acad. Sci., Chem. Sci., 1992, 104, 533 - 534.
1. S. Sarkar and S. K. Das
Synthesis of the Active Sites of Molybdoenzymes: MoO
2(VI) and MoO(IV) - Dithiolene Complexes Mimicking Enzymatic Reactions of Sulfite Oxidase
with Saturation Kinetics
Proc. Indian Acad. Sci., Chem. Sci., 1992, 104, 437 - 441.
"Perfection is Achieved Not When There Is Nothing More to Add, But When There Is Nothing Left to Take Away"