74. Babu, R., Bhargavi, G., Rajasekharan, M.V. Polyhalide ions (Br82− and I2Br62−) and Chains (···Br3−···Br2··· and ···IBr4−···) stabilised by using Cu(dafone)32+ as counter ion (dafone = 4,5-diazafluoren-9-one) (2015) European Journal of Inorganic Chemistry, 2015 (28), pp. 4689-4698. —                 DOI 73. Elahi, S.M., Rajasekharan, M.V. Spherical octanuclear clusters in a Na-Ln-dipic system - encapsulation of a nitrate ion and incorporation of water nonamers and dodecamers (2015) CrystEngComm, 17 (37), pp. 7191-7198. —                 DOI 72. Thatipamula, K.C., Bhargavi, G., Rajasekharan, M.V. Di-aqua-bridged dinuclear Cu(II) isonicotinate adducts using 2,2'-bipyridine and 1,10-phenanthroline (2015) Polyhedron, 97, pp. 182-187. —                 DOI 71. Elahi, S.M., Rajasekharan, M.V. Alkaline-earth (Mg-Ba) coordination networks built around the tris(dipicolinato)cerate(3−) ion: Highly hydrated networks that survive dehydration (2015) European Journal of Inorganic Chemistry, 2015 (1), pp. 171-178. —                 DOI 70. Biju, A.R., Rajasekharan, M.V., Bhat, S.S., Khan, A.A., Kumbhar, A.S. Synthesis, crystal structure and cytotoxicity studies of cis-dichloro(4,5- diazafluoren-9-one)platinum(II) (2014) Inorganica Chimica Acta, 423 (PB), pp. 93-97. —                 DOI 69. Prasad, T.K., Rajasekharan, M.V. Novel three-dimensional coordination polymers of lanthanides with sulfate and oxydiacetic acid (2013) Acta Crystallographica Section C: Crystal Structure Communications, 69 (12), pp. 1503-1508. —                 DOI 68. Bhargavi, G., Rajasekharan, M.V., Costes, J.-P., Tuchagues, J.-P. A new end-on azido bridged MnIII single-chain magnet and its dimeric single molecule magnet polymorph. Synthesis, structure and magnetic properties of [Mn(5-Clsalpn)N3]n and phenoxo bridged [Mn(5-Clsalpn)N3]2 (2013) Dalton Transactions, 42 (22), pp. 8113-8123. —                 DOI 67. Babu, B.K., Biju, A.R., Sunkari, S., Rajasekharan, M.V., Tuchagues, J.-P. Tetranuclear copper azido complex of 4,5-diazafluoren-9-one (2013) European Journal of Inorganic Chemistry, (9), pp. 1444-1450. —                 DOI 66. Babu, B.K., Elahi, S.M., Chary, T.K., Rajasekharan, M.V. Synthesis and structural studies of copper(II) and nickel(II) complexes containing 4,5-diazafluoren-9-one and pseudohalides: Metal ion directed isomer preference (2011) Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 50 (9-10), pp. 1318-1323. —                 65. Biju, A.R., Rajasekharan, M.V. Structure, magnetic properties, catalase activity and DFT studies of [Mn2(μ- RCOO)2(μ-OR)2]2+ type dinuclear manganese(III,III) complexes (2011) Inorganica Chimica Acta, 372 (1), pp. 275-280. —                 DOI 64. Onawumi, O.O.E., Faboya, O.O.P., Odunola, O.A., Prasad, T.K., Rajasekharan, M.V. Mixed ligand tris-chelate of copper(II) with N,N-donor ligands - Synthesis, structure and spectra of [Cu(en)(phen)2]X2·2phen·8H2O (X = Cl−, NO3−) (2011) Polyhedron, 30 (5), pp. 725-729. —                 DOI 63. Chattopadhyay, M.K., Raghu, G., Sharma, Y.V.R.K., Biju, A.R., Rajasekharan, M.V., Shivaji, S. Increase in oxidative stress at low temperature in an antarctic Bacterium (2011) Current Microbiology, 62 (2), pp. 544-546. —                 DOI 62. Prasad, T.K., Rajasekharan, M.V. Heterometallic coordination compounds of dipicolinic acid with Ce(III, IV) and Cu(II): Synthesis, crystal structure and spectral studies (2010) Inorganica Chimica Acta, 363 (12), pp. 2971-2976. —                 DOI 61. Biju, A.R., Rajasekharan, M.V. Polymorphism in the nitrate salt of the [Mn(acetyl-acetonate)2(H2O)2]+ ion (2010) Acta Crystallographica Section B: Structural Science, 66 (3), pp. 373- 379. —                 DOI 60. Onawumi, O.O., Adekunle, F.A., Ibrahim, A.O., Rajasekharan, M.V., Odunola, O.A. Synthesis, characterization, and crystal structures of [Cu(phen)2Cl]Cl·6.5H2O and [Cu(phen)2Br]Br (2010) Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 40 (2), pp. 78-83. —                 DOI 59. Biju, A.R., Rajasekharan, M.V. [Mn(acac)2(HOCH3)2]3[Ce(NO3)6]-Icosahedral anion builds a cubic network (2010) Crystal Growth and Design, 10 (1), pp. 426-429. —                 DOI 58. Prasad, T.K., Rajasekharan, M.V. Cerium(IV)-lanthanide(III)-pyridine-2,6-dicarboxylic acid system: Coordination salts, chains, and rings (2009) Inorganic Chemistry, 48 (24), pp. 11543-11550. —                 DOI 57. Bhargavi, G., Rajasekharan, M.V., Tuchagues, J.-P. Antiferromagnetic interactions through phenoxo bridges and lattice water: Synthesis, structure, and magnetic properties of new Mn(III) Schiff base complexes in combination with thiocyanate ligand (2009) Inorganica Chimica Acta, 362 (9), pp. 3247-3252. —                 DOI 56. Bhargavi, G., Rajasekharan, M.V., Costes, J.-P., Tuchagues, J.-P. Synthesis, crystal structure and magnetic properties of dimeric MnIII Schiff base complexes including pseudohalide ligands: Ferromagnetic interactions through phenoxo bridges and single molecule magnetism (2009) Polyhedron, 28 (7), pp. 1253-1260. —                 DOI 55. Biju, A.R., Rajasekharan, M.V. Unusual coordination geometries of silver(I) 4,5-diazafluoren-9-one complexes (2008) Polyhedron, 27 (9-10), pp. 2065-2068. —                 DOI 54. Prasad, T.K., Rajasekharan, M.V. Solvent dependent crystallization of isomeric chain coordination polymers in the Ce-Zn/Cd-dipic system (2008) Crystal Growth and Design, 8 (4), pp. 1346-1352. —                 DOI 53. Biju, A.R., Rajasekharan, M.V. Fluoromanganese(III) complex of phenanthroline. Distortion isomers of Mn(phen)F3(H2O) stabilised by intermolecular interactions - Crystal structures, electronic spectra and DFT calculations (2008) Journal of Molecular Structure, 875 (1-3), pp. 456-461. —                 DOI 52. Onawumi, O.O.E., Faboya, O.O.P., Odunola, O.A., Prasad, T.K., Rajasekharan, M.V. Synthesis, structure and spectral studies on mixed ligand copper(II) complexes of diimines and acetylacetonate (2008) Polyhedron, 27 (1), pp. 113-117. —                 DOI 51. Prasad, T.K., Rajasekharan, M.V. Synthesis and structural characterisation of a mixed-valent cerium complex containing a (H2O)38 cluster (2008) Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 38 (1), pp. 55-61. —                 DOI 50. Balkis Ameen, K., Rajasekar, K., Rajasekharan, T., Rajasekharan, M.V. The effect of heat-treatment on the physico-chemical properties of silica aerogel prepared by sub-critical drying technique (2008) Journal of Sol-Gel Science and Technology, 45 (1), pp. 9-15. —                 DOI 49. Prasad, T.K., Rajasekharan, M.V., Costes, J.-P. A cubic 3d-4f structure with only ferromagnetic Gd-Mn interactions (2007) Angewandte Chemie - International Edition, 46 (16), pp. 2851-2854. —                 DOI 48. Prasad, T.K., Rajasekharan, M.V. [M(dipicH2)(H2O)3]2+, M = Ni, Cu, Zn (dipicH2 = dipicolinic acid) - A combined crystallographic, spectroscopic and computational study (2007) Polyhedron, 26 (7), pp. 1364-1372. —                 DOI 47. Onawumi, O.O.E., Faboya, O.O.P., Odunola, O.A., Prasad, T.K., Rajasekharan, M.V. Solvent water tapes in two hydrates of μ-oxo-bis[bis(2,2'- bipyridine- κ2N,N')-(sulfato-κO)iron(III)] (2006) Acta Crystallographica Section C: Crystal Structure Communications, 62 (10), pp. m480-m483. —                 DOI 46. Balkis Ameen, K., Rajasekharan, T., Rajasekharan, M.V. Grain size dependence of physico-optical properties of nanometallic silver in silica aerogel matrix (2006) Journal of Non-Crystalline Solids, 352 (8), pp. 737-746. —                 DOI 45. Prasad, T.K., Rajasekharan, M.V. A novel water octamer in Ce(dipic)2(H2O)3·4H2O: Crystallographic, thermal, and theoretical studies (2006) Crystal Growth and Design, 6 (2), pp. 488-491. —                 DOI 44. Khan, M.A.H., Prasad, T.K., Rajasekharan, M.V. Silver(I) complexes of 2-(2-aminoethyl)pyridine: Nitrate and perchlorate salts of bis[μ-2-(2-aminoethyl)pyridine-κ2N:N']disilver(I) (2005) Acta Crystallographica Section C: Crystal Structure Communications, 61 (6), pp. m281-m283. —                 DOI 43. Prasad, T.K., Rajasekharan, M.V. Inter-conversion of 1-D coordination polymers in the Ce-Sr-dipicH2 system (dipicH2 = dipicolinic acid) (2005) Inorganic Chemistry Communications, 8 (12), pp. 1116-1119. —                 DOI 42. Prasad, T.K., Sailaja, S., Rajasekharan, M.V. 1-Dimensional and 2-dimensional coordination network structures in the Ba-Ce- dipicH2 system (dipicH2 = dipicolinic acid) (2005) Polyhedron, 24 (12), pp. 1487-1496. —                 DOI 41. Sailaja, S., Rajasekharan, M.V. Synthesis and structure of coordination polymers of Ag(I) with isomeric (aminomethyl)pyridines. Formation of a novel circular helicate and 2-D networks via Ag···Ag contacts and coordination shell expansion under anion control (2003) Inorganic Chemistry, 42 (18), pp. 5675-5684. —                 DOI 40. Sailaja, S., Rajender Reddy, K., Rajasekharan, M.V., Hureau, C., RiviC(re, E., Cano, J., Girerd, J.-J. Synthesis, structure, and magnetic properties of [MnIII(salpn)NCS]n, a helical polymer (2003) Inorganic Chemistry, 42 (1), pp. 180-186. —                 DOI 39. Sailaja, S., Swarnabala, G., Rajasekharan, M.V. Complexes of AgI with cationic ligands: Bis[(pyridylmethyl)-ammonio]silver(I) salts (2001) Acta Crystallographica Section C: Crystal Structure Communications, 57 (10), pp. 1162-1165. —                 DOI 38. Sailaja, S., Rajasekharan, M.V. One-dimensional coordination polymers of silver(I) with aminomethylpyridines. Example of a triple helical infinite chain (2000) Inorganic Chemistry, 39 (20), pp. 4586-4590. —                 DOI 37. Ramalakshmi, D., Rajasekharan, M.V. Crystallographic disorder in mixed-valent dioxo-bridged MnIII,IV complexes. [Mn2O2(bpy)4]-[Ce(NO3)6]·5H2O (1999) Acta Crystallographica Section B: Structural Science, 55 (2), pp. 186- 191. —                 DOI 36. Ramalakshmi, D., Reddy, K.R., Padmavathy, D., Rajasekharan, M.V., Arulsamy, N., Hodgson, D.J. Polyiodides of transition metal trischelate cations: Syntheses, structures, and spectral and electrical conductivity studies of [Mn(phen)3](I3)2 and [Mn(bpy)3](I3)1.5(I8)0.25 (1999) Inorganica Chimica Acta, 284 (2), pp. 158-166. —                 DOI 35. Rajender Reddy, K., Rajasekharan, M.V., Tuchagues, J.-P. Synthesis, Structure, and Magnetic Properties of Mn(salpn)N3, a Helical Polymer, and Fe(salpn)N3, a Ferromagnetically Coupled Dimer (salpnH2 = N,N'- bis(Salicylidene)-l,3-diaminopropane) (1998) Inorganic Chemistry, 37 (23), pp. 5978-5982. —                 DOI 34. Vanhelmont, F.W.M., Rajasekharan, M.V., Güdel, H.U., Capelli, S.C., Hauser, J., Bürgi, H.-B. Influence of electron donor and acceptor substituents on the excited state properties of rhenium(I) tetracarbonyl chelate complexes (1998) Journal of the Chemical Society - Dalton Transactions, (17), pp. 2893- 2900. —                 DOI 33. Swarnabala, G., Rajasekharan, M.V. [Ca(dipicH2)(OH2)3][Ce(dipic)3]·5H2O: A One-Dimensional Coordination Polymer with Alternating CeN3O6 and CaNO7 Polyhedra (dipicH2 = Pyridine-2,6-dicarboxylic Acid) (1998) Inorganic Chemistry, 37 (7), pp. 1483-1485. —                 DOI 32. Menon, S., Rajasekharan, M.V. Bis chelate Cu(II) complexes of dafone - Synthesis, structural, EPR and optical spectral studies (1998) Polyhedron, 17 (15), pp. 2463-2476. —                 DOI 31. Menon, S., Rajasekharan, M.V., Tuchagues, J.-P. Synthesis, Crystal Structure, Magnetic Properties, and EPR of Cu(bp3ca)Br2·H2O (bp3ca = 2,2'-Bipyridine-3,3'-dicarboxylic Acid). Ferromagnetic Interactions via Unsymmetrical Bromide Bridges (1997) Inorganic Chemistry, 36 (20), pp. 4341-4346. —                 DOI 30. Menon, S., Rajasekharan, M.V. A Channel-Forming Polyiodide Network in [Cu(dafone)3]I12. A Tris Chelate of Dafone and a New Planar Structure for the I122- Ion (Dafone = 4,5-Diazafluoren- 9-one) (1997) Inorganic Chemistry, 36 (22), pp. 4983-4987. —                 DOI 29. Swarnabala, G., Rajasekharan, M.V., Padhye, S. Origin of the hyperfine anisotropy in a Mn(IV) complex containing paramagnetic ligands (1997) Chemical Physics Letters, 267 (5-6), pp. 539-544. —                 DOI 28. Swarnabala, G., Rajasekharan, M.V. Structure of [2-(aminomethyl)pyridine]silver(I) nitrate and EPR studies of its oxidation product (1997) Polyhedron, 16 (6), pp. 921-925. —                 DOI 27. Rajender Reddy, K., Rajasekharan, M.V., Arulsamy, N., Hodgson, D.J. Synthesis and Structural Investigations of [Mn3O4(phen)4(H2O) 2](NO3)4·2.5H2O: A Water-Bound Complex Obtained by Cerium(IV) Oxidation (1996) Inorganic Chemistry, 35 (8), pp. 2283-2286. —                 DOI 26. Reddy, K.R., Rajasekharan, M.V., Sukumar, S. Synthesis and structural characterization of an unsymmetrical (μ-oxo)-di-(μ -acetato) manganese(III,III) complex ([Mn2O(OAc)2(H2O)(NO3)(bpy)2](ClO4)· CH3COOH) (1996) Polyhedron, 15 (23), pp. 4161-4168. —                 DOI 25. Venkatalakshmi, N., Rajasekharan, M.V. EPR studies of copper(II) complexes of phenanthraquinonedioxime and benzoquinonedioxime (1996) Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 35 (9), pp. 779-780. —                 24. Chandramouli, G.V.R., Balagopalakrishna, C., Rajasekharan, M.V., Manoharan, P.T. Fitting of magnetic susceptibility data as a function of temperature of various spin systems - A fortran program (1996) Computers and Chemistry, 20 (3), pp. 353-358. —                 DOI 23. Swarnabala, G., Rajasekharan, M.V. Influence of intermolecular interactions on coordination geometry - Crystal and molecular structure of Ag(dmp)NO3·2H2O (dmp = 2,9-dimethyl-1,10- phenanthroline) (1996) Polyhedron, 15 (19), pp. 3197-3201. —                 DOI 22. Menon, S., Rajasekharan, M.V. Magnetostructural correlations on Cu(II) complexes of bipyridyl-3,3'- dicarboxylic acid (BP-3-CA) (1996) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 108 (3), p. 293. —                 DOI 21. Ramalakshmi, D., Swarnabala, G., Rajasekharan, M.V. Synthesis, crystal structure and EPR simulation of a water stable binuclear di- μ-oxo Mn(III, IV) complex (1996) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 108 (3), pp. 291-292. —                 DOI 20. Venkatalakshmi, N., Rajasekharan, M.V. EPR of the Co(II) complexes of phenanthraquinonedioxime and benzoquinonedioxime. Formation of dioxygen adducts in the solid state (1995) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 107 (4), pp. 327-333. —                 DOI 19. Menon, S., Balagopalakrishna, C., Rajasekharan, M.V., Ramakrishna, B.L. Synthesis, crystal structure, magnetic susceptibility, and single-crystal EPR studies of [dafoneH2][(CuCl3H2O)Cl] (1994) Inorganic Chemistry, 33 (5), pp. 950-954. —                 DOI 18. Reddy, K.R., Rajasekharan, M.V., Padhye, S., Dahan, F., Tuchagues, J.-P. Modeling the photosynthetic water oxidation center: Synthesis, structure, and magnetic properties of [Mn2(μ-O)2(μ-OAc)(H2O)2(bipy)2](ClO4)3·H2O (1994) Inorganic Chemistry, 33 (3), pp. 428-433. —                 DOI 17. Swarnabala, G., Reddy, K.R., Tirunagar, J., Rajasekharan, M.V. Mononuclear manganese(III) aquo complexes. Crystal and molecular structures of [Mn(phen)(OH2)Cl3] and [Mn(acac)2(OH2)2]ClO4 ·2H2O (acacH = acetylacetone, phen = 1,10-phenanthroline) (1994) Transition Metal Chemistry, 19 (5), pp. 506-508. —                 DOI 16. Reddy, K.R., Rajasekharan, M.V. A mononuclear bis-chelate complex of manganese(III) with 1,10-phenanthroline. Crystal and molecular structure of [Mn(phen)2Cl2]NO3·2.5CH3COOH (1994) Polyhedron, 13 (5), pp. 765-769. —                 DOI 15. Balagopalakrishna, C., Rajasekharan, M.V., Bott, S., Atwood, J.L., Ramakrishna, B.L. Synthesis, crystal structure, magnetic susceptibility, and single-crystal EPR studies of bis(diazafluorenone)dichlorocopper(II): A novel Cu(NN)2X2 system with an unusual distortion (1992) Inorganic Chemistry, 31 (13), pp. 2843-2846. —                 DOI 14. Venkatalakshmi, N., Rajasekharan, M.V., Mathews, I.I. Crystal and molecular structure of nitrato(6,6'-2-dimethyl-2,2b2- bipyridine)silver(I). A dimer held by stacking and silver-silver interactions (1992) Transition Metal Chemistry, 17 (5), pp. 455-457. —                 DOI 13. Swarnabala, G., Rajasekharan, M.V. Unsymmetrically ligated dioxobridged Mn(III, IV) complexes-synthesis and spectral studies (1990) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 102 (2), pp. 87-98. —                 DOI 12. Swarnabala, G., Rajasekharan, M.V. Multiline ESR from a Mn(III,III) complex? (1990) Inorganica Chimica Acta, 168 (2), pp. 167-168. —                 DOI 11. Balagopalakrishna, C., Rajasekharan, M.V. Long-range exchange interaction in (2,2-bipyridine-3,3-dicarboxylic acid)dichlorocopper(II) monohydrate via lattice water: Single-crystal EPR studies (1990) Physical Review B, 42 (13), pp. 7794-7802. —                 DOI 10. Swarnabala, G., Rajasekharan, M.V. Silver(II) complexes of hindered N-heterocyclic ligands. Electron spin resonance of nitrato(6,6b2-dimethyl-2,2b2-bipyridine)silver(II) and nitrato(2,9- dimethyl-1,10-phenanthroline)silver(II) ions (1989) Inorganic Chemistry, 28 (4), pp. 662-666. —                 DOI 9. Rajasekharan, M.V., Chandramouli, G.V.R., Manoharan, P.T. Polarized electronic spectral studies on some diethyldithiocarbamate complexes of Ni(II) and Pd(II) (1989) Chemical Physics Letters, 162 (1-2), pp. 110-116. —                 DOI 8. Knochenmuss, R., Reber, C., Rajasekharan, M.V., Gudel, H.U. Broadband near-infrared luminescence of Cr+3 in the elpasolite lattices Cs2NaInCl6, Cs2NaYCl6, and Cs(sub>2NaYBr6 (1986) The Journal of Chemical Physics, 85 (8), pp. 4280-4289. —                 DOI 7. Swarnabala, G., Umashankar, M., Rajasekharan, M.V. EPR studies of mixed valence interactions in Mn(III,IV) complexes. (1984) Proceedings - XXIInd Congress AMPERE on Magnetic Resonance and Related Phenomena. pp. 457-458. —                 6. Koelle, U., Fuss, B., Rajasekharan, M.V., Ramakrishna, B.L., Ammeter, J.H., Boehm, M.C. Pentamethylcyclopentadienyl transition-matal complexes. Electrochemistry of transition-metal pi-complexes. 7. Cyclopentadienyl(arene)cobalt cations: Preparation, electrochemical reduction, and spectroscopic investigation of the paramagnetic d7 monocations. (1984) Journal of the American Chemical Society, 106 (15), pp. 4152-4160. —                 DOI 5. Rajasekharan, M.V., Bucher, R., Deiss, E., Zoller, L., Salzer, A.K., Moser, E., Weber, J., Ammeter, J.H. EPR study of the electronic structure and dynamic Jahn-Teller effect in nickelocenium cation. (1983) Journal of the American Chemical Society, 105 (26), pp. 7516-7522. —                 DOI 4. Rajasekharan, M.V., Giezynski, S., Ammeter, J.H., Oswald, N., Michaud, P., Hamon, J.R., Astruc, D. EPR studies of the electronic structure and dynamic Jahn-Teller effect in iron(I) sandwich compounds (1982) Journal of the American Chemical Society, 104 (9), pp. 2400-2407. —                 DOI 3. Rajasekharan, M.V., Manoharan, P.T. EPR studies on copper and cobalt triazene-1-oxide complexes in a frozen nematic medium. (1980) Molecular crystals and liquid crystals, 59 (3-4), pp. 197-205. —                 DOI 2. Rajasekharan, M.V., Varughese, K.I., Manoharan, P.T. Crystal and molecular structure of two crystalline modifications of bis[1- methyl-3-(2-chloro-6-methylphenyl)triazine 1-oxidato]nickel(II), NiBPT - A bis chelate with a five-membered Ni-N-O ring (1979) Inorganic Chemistry, 18 (8), pp. 2221-2226. —                 DOI 1. Rajasekharan, M.V., Sethulakshmi, C.N., Manoharan, P.T., Güdel, H. Polarized optical absorption studies on copper and silver diethyldithiocarbamates (1976) Inorganic Chemistry, 15 (11), pp. 2657-2662. —                 DOI