74. Babu, R., Bhargavi, G., Rajasekharan, M.V.
Polyhalide ions (Br82− and I2Br62−) and Chains (···Br3···Br2··· and ···IBr4···) stabilised by using Cu(dafone)32+ as counter ion (dafone = 4,5-diazafluoren-9-one)
(2015) European Journal of Inorganic Chemistry, 2015 (28), pp. 4689-4698.
                 DOI

73. Elahi, S.M., Rajasekharan, M.V.
Spherical octanuclear clusters in a Na-Ln-dipic system - encapsulation of a nitrate ion and incorporation of water nonamers and dodecamers
(2015) CrystEngComm, 17 (37), pp. 7191-7198.
                 DOI

72. Thatipamula, K.C., Bhargavi, G., Rajasekharan, M.V.
Di-aqua-bridged dinuclear Cu(II) isonicotinate adducts using 2,2'-bipyridine and 1,10-phenanthroline
(2015) Polyhedron, 97, pp. 182-187.
                 DOI

71. Elahi, S.M., Rajasekharan, M.V.
Alkaline-earth (Mg-Ba) coordination networks built around the tris(dipicolinato)cerate(3−) ion: Highly hydrated networks that survive dehydration
(2015) European Journal of Inorganic Chemistry, 2015 (1), pp. 171-178.
                 DOI

70. Biju, A.R., Rajasekharan, M.V., Bhat, S.S., Khan, A.A., Kumbhar, A.S.
Synthesis, crystal structure and cytotoxicity studies of cis-dichloro(4,5- diazafluoren-9-one)platinum(II)
(2014) Inorganica Chimica Acta, 423 (PB), pp. 93-97.
                 DOI

69. Prasad, T.K., Rajasekharan, M.V.
Novel three-dimensional coordination polymers of lanthanides with sulfate and oxydiacetic acid
(2013) Acta Crystallographica Section C: Crystal Structure Communications, 69 (12), pp. 1503-1508.
                 DOI

68. Bhargavi, G., Rajasekharan, M.V., Costes, J.-P., Tuchagues, J.-P.
A new end-on azido bridged MnIII single-chain magnet and its dimeric single molecule magnet polymorph. Synthesis, structure and magnetic properties of [Mn(5-Clsalpn)N3]n and phenoxo bridged [Mn(5-Clsalpn)N3]2
(2013) Dalton Transactions, 42 (22), pp. 8113-8123.
                 DOI

67. Babu, B.K., Biju, A.R., Sunkari, S., Rajasekharan, M.V., Tuchagues, J.-P.
Tetranuclear copper azido complex of 4,5-diazafluoren-9-one
(2013) European Journal of Inorganic Chemistry, (9), pp. 1444-1450.
                 DOI

66. Babu, B.K., Elahi, S.M., Chary, T.K., Rajasekharan, M.V.
Synthesis and structural studies of copper(II) and nickel(II) complexes containing 4,5-diazafluoren-9-one and pseudohalides: Metal ion directed isomer preference
(2011) Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 50 (9-10), pp. 1318-1323.
                

65. Biju, A.R., Rajasekharan, M.V.
Structure, magnetic properties, catalase activity and DFT studies of [Mn2(μ- RCOO)2(μ-OR)2]2+ type dinuclear manganese(III,III) complexes
(2011) Inorganica Chimica Acta, 372 (1), pp. 275-280.
                 DOI

64. Onawumi, O.O.E., Faboya, O.O.P., Odunola, O.A., Prasad, T.K., Rajasekharan, M.V.
Mixed ligand tris-chelate of copper(II) with N,N-donor ligands - Synthesis, structure and spectra of [Cu(en)(phen)2]X2·2phen·8H2O (X = Cl, NO3)
(2011) Polyhedron, 30 (5), pp. 725-729.
                 DOI

63. Chattopadhyay, M.K., Raghu, G., Sharma, Y.V.R.K., Biju, A.R., Rajasekharan, M.V., Shivaji, S.
Increase in oxidative stress at low temperature in an antarctic Bacterium
(2011) Current Microbiology, 62 (2), pp. 544-546.
                 DOI

62. Prasad, T.K., Rajasekharan, M.V.
Heterometallic coordination compounds of dipicolinic acid with Ce(III, IV) and Cu(II): Synthesis, crystal structure and spectral studies
(2010) Inorganica Chimica Acta, 363 (12), pp. 2971-2976.
                 DOI

61. Biju, A.R., Rajasekharan, M.V.
Polymorphism in the nitrate salt of the [Mn(acetyl-acetonate)2(H2O)2]+ ion
(2010) Acta Crystallographica Section B: Structural Science, 66 (3), pp. 373- 379.
                 DOI

60. Onawumi, O.O., Adekunle, F.A., Ibrahim, A.O., Rajasekharan, M.V., Odunola, O.A.
Synthesis, characterization, and crystal structures of [Cu(phen)2Cl]Cl·6.5H2O and [Cu(phen)2Br]Br
(2010) Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 40 (2), pp. 78-83.
                 DOI

59. Biju, A.R., Rajasekharan, M.V.
[Mn(acac)2(HOCH3)2]3[Ce(NO3)6]-Icosahedral anion builds a cubic network
(2010) Crystal Growth and Design, 10 (1), pp. 426-429.
                 DOI

58. Prasad, T.K., Rajasekharan, M.V.
Cerium(IV)-lanthanide(III)-pyridine-2,6-dicarboxylic acid system: Coordination salts, chains, and rings
(2009) Inorganic Chemistry, 48 (24), pp. 11543-11550.
                 DOI

57. Bhargavi, G., Rajasekharan, M.V., Tuchagues, J.-P.
Antiferromagnetic interactions through phenoxo bridges and lattice water: Synthesis, structure, and magnetic properties of new Mn(III) Schiff base complexes in combination with thiocyanate ligand
(2009) Inorganica Chimica Acta, 362 (9), pp. 3247-3252.
                 DOI

56. Bhargavi, G., Rajasekharan, M.V., Costes, J.-P., Tuchagues, J.-P.
Synthesis, crystal structure and magnetic properties of dimeric MnIII Schiff base complexes including pseudohalide ligands: Ferromagnetic interactions through phenoxo bridges and single molecule magnetism
(2009) Polyhedron, 28 (7), pp. 1253-1260.
                 DOI

55. Biju, A.R., Rajasekharan, M.V.
Unusual coordination geometries of silver(I) 4,5-diazafluoren-9-one complexes
(2008) Polyhedron, 27 (9-10), pp. 2065-2068.
                 DOI

54. Prasad, T.K., Rajasekharan, M.V.
Solvent dependent crystallization of isomeric chain coordination polymers in the Ce-Zn/Cd-dipic system
(2008) Crystal Growth and Design, 8 (4), pp. 1346-1352.
                 DOI

53. Biju, A.R., Rajasekharan, M.V.
Fluoromanganese(III) complex of phenanthroline. Distortion isomers of Mn(phen)F3(H2O) stabilised by intermolecular interactions - Crystal structures, electronic spectra and DFT calculations
(2008) Journal of Molecular Structure, 875 (1-3), pp. 456-461.
                 DOI

52. Onawumi, O.O.E., Faboya, O.O.P., Odunola, O.A., Prasad, T.K., Rajasekharan, M.V.
Synthesis, structure and spectral studies on mixed ligand copper(II) complexes of diimines and acetylacetonate
(2008) Polyhedron, 27 (1), pp. 113-117.
                 DOI

51. Prasad, T.K., Rajasekharan, M.V.
Synthesis and structural characterisation of a mixed-valent cerium complex containing a (H2O)38 cluster
(2008) Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 38 (1), pp. 55-61.
                 DOI

50. Balkis Ameen, K., Rajasekar, K., Rajasekharan, T., Rajasekharan, M.V.
The effect of heat-treatment on the physico-chemical properties of silica aerogel prepared by sub-critical drying technique
(2008) Journal of Sol-Gel Science and Technology, 45 (1), pp. 9-15.
                 DOI

49. Prasad, T.K., Rajasekharan, M.V., Costes, J.-P.
A cubic 3d-4f structure with only ferromagnetic Gd-Mn interactions
(2007) Angewandte Chemie - International Edition, 46 (16), pp. 2851-2854.
                 DOI

48. Prasad, T.K., Rajasekharan, M.V.
[M(dipicH2)(H2O)3]2+, M = Ni, Cu, Zn (dipicH2 = dipicolinic acid) - A combined crystallographic, spectroscopic and computational study
(2007) Polyhedron, 26 (7), pp. 1364-1372.
                 DOI

47. Onawumi, O.O.E., Faboya, O.O.P., Odunola, O.A., Prasad, T.K., Rajasekharan, M.V.
Solvent water tapes in two hydrates of μ-oxo-bis[bis(2,2'- bipyridine- κ2N,N')-(sulfato-κO)iron(III)]
(2006) Acta Crystallographica Section C: Crystal Structure Communications, 62 (10), pp. m480-m483.
                 DOI

46. Balkis Ameen, K., Rajasekharan, T., Rajasekharan, M.V.
Grain size dependence of physico-optical properties of nanometallic silver in silica aerogel matrix
(2006) Journal of Non-Crystalline Solids, 352 (8), pp. 737-746.
                 DOI

45. Prasad, T.K., Rajasekharan, M.V.
A novel water octamer in Ce(dipic)2(H2O)3·4H2O: Crystallographic, thermal, and theoretical studies
(2006) Crystal Growth and Design, 6 (2), pp. 488-491.
                 DOI

44. Khan, M.A.H., Prasad, T.K., Rajasekharan, M.V.
Silver(I) complexes of 2-(2-aminoethyl)pyridine: Nitrate and perchlorate salts of bis[μ-2-(2-aminoethyl)pyridine-κ2N:N']disilver(I)
(2005) Acta Crystallographica Section C: Crystal Structure Communications, 61 (6), pp. m281-m283.
                 DOI

43. Prasad, T.K., Rajasekharan, M.V.
Inter-conversion of 1-D coordination polymers in the Ce-Sr-dipicH2 system (dipicH2 = dipicolinic acid)
(2005) Inorganic Chemistry Communications, 8 (12), pp. 1116-1119.
                 DOI

42. Prasad, T.K., Sailaja, S., Rajasekharan, M.V.
1-Dimensional and 2-dimensional coordination network structures in the Ba-Ce- dipicH2 system (dipicH2 = dipicolinic acid)
(2005) Polyhedron, 24 (12), pp. 1487-1496.
                 DOI

41. Sailaja, S., Rajasekharan, M.V.
Synthesis and structure of coordination polymers of Ag(I) with isomeric (aminomethyl)pyridines. Formation of a novel circular helicate and 2-D networks via Ag···Ag contacts and coordination shell expansion under anion control
(2003) Inorganic Chemistry, 42 (18), pp. 5675-5684.
                 DOI

40. Sailaja, S., Rajender Reddy, K., Rajasekharan, M.V., Hureau, C., RiviC(re, E., Cano, J., Girerd, J.-J.
Synthesis, structure, and magnetic properties of [MnIII(salpn)NCS]n, a helical polymer
(2003) Inorganic Chemistry, 42 (1), pp. 180-186.
                 DOI

39. Sailaja, S., Swarnabala, G., Rajasekharan, M.V.
Complexes of AgI with cationic ligands: Bis[(pyridylmethyl)-ammonio]silver(I) salts
(2001) Acta Crystallographica Section C: Crystal Structure Communications, 57 (10), pp. 1162-1165.
                 DOI

38. Sailaja, S., Rajasekharan, M.V.
One-dimensional coordination polymers of silver(I) with aminomethylpyridines. Example of a triple helical infinite chain
(2000) Inorganic Chemistry, 39 (20), pp. 4586-4590.
                 DOI

37. Ramalakshmi, D., Rajasekharan, M.V.
Crystallographic disorder in mixed-valent dioxo-bridged MnIII,IV complexes. [Mn2O2(bpy)4]-[Ce(NO3)6]·5H2O
(1999) Acta Crystallographica Section B: Structural Science, 55 (2), pp. 186- 191.
                 DOI

36. Ramalakshmi, D., Reddy, K.R., Padmavathy, D., Rajasekharan, M.V., Arulsamy, N., Hodgson, D.J.
Polyiodides of transition metal trischelate cations: Syntheses, structures, and spectral and electrical conductivity studies of [Mn(phen)3](I3)2 and [Mn(bpy)3](I3)1.5(I8)0.25
(1999) Inorganica Chimica Acta, 284 (2), pp. 158-166.
                 DOI

35. Rajender Reddy, K., Rajasekharan, M.V., Tuchagues, J.-P.
Synthesis, Structure, and Magnetic Properties of Mn(salpn)N3, a Helical Polymer, and Fe(salpn)N3, a Ferromagnetically Coupled Dimer (salpnH2 = N,N'- bis(Salicylidene)-l,3-diaminopropane)
(1998) Inorganic Chemistry, 37 (23), pp. 5978-5982.
                 DOI

34. Vanhelmont, F.W.M., Rajasekharan, M.V., Güdel, H.U., Capelli, S.C., Hauser, J., Bürgi, H.-B.
Influence of electron donor and acceptor substituents on the excited state properties of rhenium(I) tetracarbonyl chelate complexes
(1998) Journal of the Chemical Society - Dalton Transactions, (17), pp. 2893- 2900.
                 DOI

33. Swarnabala, G., Rajasekharan, M.V.
[Ca(dipicH2)(OH2)3][Ce(dipic)3]·5H2O: A One-Dimensional Coordination Polymer with Alternating CeN3O6 and CaNO7 Polyhedra (dipicH2 = Pyridine-2,6-dicarboxylic Acid)
(1998) Inorganic Chemistry, 37 (7), pp. 1483-1485.
                 DOI

32. Menon, S., Rajasekharan, M.V.
Bis chelate Cu(II) complexes of dafone - Synthesis, structural, EPR and optical spectral studies
(1998) Polyhedron, 17 (15), pp. 2463-2476.
                 DOI

31. Menon, S., Rajasekharan, M.V., Tuchagues, J.-P.
Synthesis, Crystal Structure, Magnetic Properties, and EPR of Cu(bp3ca)Br2·H2O (bp3ca = 2,2'-Bipyridine-3,3'-dicarboxylic Acid). Ferromagnetic Interactions via Unsymmetrical Bromide Bridges
(1997) Inorganic Chemistry, 36 (20), pp. 4341-4346.
                 DOI

30. Menon, S., Rajasekharan, M.V.
A Channel-Forming Polyiodide Network in [Cu(dafone)3]I12. A Tris Chelate of Dafone and a New Planar Structure for the I122- Ion (Dafone = 4,5-Diazafluoren- 9-one)
(1997) Inorganic Chemistry, 36 (22), pp. 4983-4987.
                 DOI

29. Swarnabala, G., Rajasekharan, M.V., Padhye, S.
Origin of the hyperfine anisotropy in a Mn(IV) complex containing paramagnetic ligands
(1997) Chemical Physics Letters, 267 (5-6), pp. 539-544.
                 DOI

28. Swarnabala, G., Rajasekharan, M.V.
Structure of [2-(aminomethyl)pyridine]silver(I) nitrate and EPR studies of its oxidation product
(1997) Polyhedron, 16 (6), pp. 921-925.
                 DOI

27. Rajender Reddy, K., Rajasekharan, M.V., Arulsamy, N., Hodgson, D.J.
Synthesis and Structural Investigations of [Mn3O4(phen)4(H2O) 2](NO3)4·2.5H2O: A Water-Bound Complex Obtained by Cerium(IV) Oxidation
(1996) Inorganic Chemistry, 35 (8), pp. 2283-2286.
                 DOI

26. Reddy, K.R., Rajasekharan, M.V., Sukumar, S.
Synthesis and structural characterization of an unsymmetrical (μ-oxo)-di-(μ -acetato) manganese(III,III) complex ([Mn2O(OAc)2(H2O)(NO3)(bpy)2](ClO4)· CH3COOH)
(1996) Polyhedron, 15 (23), pp. 4161-4168.
                 DOI

25. Venkatalakshmi, N., Rajasekharan, M.V.
EPR studies of copper(II) complexes of phenanthraquinonedioxime and benzoquinonedioxime
(1996) Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 35 (9), pp. 779-780.
                

24. Chandramouli, G.V.R., Balagopalakrishna, C., Rajasekharan, M.V., Manoharan, P.T.
Fitting of magnetic susceptibility data as a function of temperature of various spin systems - A fortran program
(1996) Computers and Chemistry, 20 (3), pp. 353-358.
                 DOI

23. Swarnabala, G., Rajasekharan, M.V.
Influence of intermolecular interactions on coordination geometry - Crystal and molecular structure of Ag(dmp)NO3·2H2O (dmp = 2,9-dimethyl-1,10- phenanthroline)
(1996) Polyhedron, 15 (19), pp. 3197-3201.
                 DOI

22. Menon, S., Rajasekharan, M.V.
Magnetostructural correlations on Cu(II) complexes of bipyridyl-3,3'- dicarboxylic acid (BP-3-CA)
(1996) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 108 (3), p. 293.
                 DOI

21. Ramalakshmi, D., Swarnabala, G., Rajasekharan, M.V.
Synthesis, crystal structure and EPR simulation of a water stable binuclear di- μ-oxo Mn(III, IV) complex
(1996) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 108 (3), pp. 291-292.
                 DOI

20. Venkatalakshmi, N., Rajasekharan, M.V.
EPR of the Co(II) complexes of phenanthraquinonedioxime and benzoquinonedioxime. Formation of dioxygen adducts in the solid state
(1995) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 107 (4), pp. 327-333.
                 DOI

19. Menon, S., Balagopalakrishna, C., Rajasekharan, M.V., Ramakrishna, B.L.
Synthesis, crystal structure, magnetic susceptibility, and single-crystal EPR studies of [dafoneH2][(CuCl3H2O)Cl]
(1994) Inorganic Chemistry, 33 (5), pp. 950-954.
                 DOI

18. Reddy, K.R., Rajasekharan, M.V., Padhye, S., Dahan, F., Tuchagues, J.-P.
Modeling the photosynthetic water oxidation center: Synthesis, structure, and magnetic properties of [Mn2(μ-O)2(μ-OAc)(H2O)2(bipy)2](ClO4)3·H2O
(1994) Inorganic Chemistry, 33 (3), pp. 428-433.
                 DOI

17. Swarnabala, G., Reddy, K.R., Tirunagar, J., Rajasekharan, M.V.
Mononuclear manganese(III) aquo complexes. Crystal and molecular structures of [Mn(phen)(OH2)Cl3] and [Mn(acac)2(OH2)2]ClO4 ·2H2O (acacH = acetylacetone, phen = 1,10-phenanthroline)
(1994) Transition Metal Chemistry, 19 (5), pp. 506-508.
                 DOI

16. Reddy, K.R., Rajasekharan, M.V.
A mononuclear bis-chelate complex of manganese(III) with 1,10-phenanthroline. Crystal and molecular structure of [Mn(phen)2Cl2]NO3·2.5CH3COOH
(1994) Polyhedron, 13 (5), pp. 765-769.
                 DOI

15. Balagopalakrishna, C., Rajasekharan, M.V., Bott, S., Atwood, J.L., Ramakrishna, B.L.
Synthesis, crystal structure, magnetic susceptibility, and single-crystal EPR studies of bis(diazafluorenone)dichlorocopper(II): A novel Cu(NN)2X2 system with an unusual distortion
(1992) Inorganic Chemistry, 31 (13), pp. 2843-2846.
                 DOI

14. Venkatalakshmi, N., Rajasekharan, M.V., Mathews, I.I.
Crystal and molecular structure of nitrato(6,6'-2-dimethyl-2,2b2- bipyridine)silver(I). A dimer held by stacking and silver-silver interactions
(1992) Transition Metal Chemistry, 17 (5), pp. 455-457.
                 DOI

13. Swarnabala, G., Rajasekharan, M.V.
Unsymmetrically ligated dioxobridged Mn(III, IV) complexes-synthesis and spectral studies
(1990) Proceedings of the Indian Academy of Sciences - Chemical Sciences, 102 (2), pp. 87-98.
                 DOI

12. Swarnabala, G., Rajasekharan, M.V.
Multiline ESR from a Mn(III,III) complex?
(1990) Inorganica Chimica Acta, 168 (2), pp. 167-168.
                 DOI

11. Balagopalakrishna, C., Rajasekharan, M.V.
Long-range exchange interaction in (2,2-bipyridine-3,3-dicarboxylic acid)dichlorocopper(II) monohydrate via lattice water: Single-crystal EPR studies
(1990) Physical Review B, 42 (13), pp. 7794-7802.
                 DOI

10. Swarnabala, G., Rajasekharan, M.V.
Silver(II) complexes of hindered N-heterocyclic ligands. Electron spin resonance of nitrato(6,6b2-dimethyl-2,2b2-bipyridine)silver(II) and nitrato(2,9- dimethyl-1,10-phenanthroline)silver(II) ions
(1989) Inorganic Chemistry, 28 (4), pp. 662-666.
                 DOI

9. Rajasekharan, M.V., Chandramouli, G.V.R., Manoharan, P.T.
Polarized electronic spectral studies on some diethyldithiocarbamate complexes of Ni(II) and Pd(II)
(1989) Chemical Physics Letters, 162 (1-2), pp. 110-116.
                 DOI

8. Knochenmuss, R., Reber, C., Rajasekharan, M.V., Gudel, H.U.
Broadband near-infrared luminescence of Cr+3 in the elpasolite lattices Cs2NaInCl6, Cs2NaYCl6, and Cs(sub>2NaYBr6
(1986) The Journal of Chemical Physics, 85 (8), pp. 4280-4289.
                 DOI

7. Swarnabala, G., Umashankar, M., Rajasekharan, M.V.
EPR studies of mixed valence interactions in Mn(III,IV) complexes.
(1984) Proceedings - XXIInd Congress AMPERE on Magnetic Resonance and Related Phenomena. pp. 457-458.
                

6. Koelle, U., Fuss, B., Rajasekharan, M.V., Ramakrishna, B.L., Ammeter, J.H., Boehm, M.C.
Pentamethylcyclopentadienyl transition-matal complexes. Electrochemistry of transition-metal pi-complexes. 7. Cyclopentadienyl(arene)cobalt cations: Preparation, electrochemical reduction, and spectroscopic investigation of the paramagnetic d7 monocations.
(1984) Journal of the American Chemical Society, 106 (15), pp. 4152-4160.
                 DOI

5. Rajasekharan, M.V., Bucher, R., Deiss, E., Zoller, L., Salzer, A.K., Moser, E., Weber, J., Ammeter, J.H.
EPR study of the electronic structure and dynamic Jahn-Teller effect in nickelocenium cation.
(1983) Journal of the American Chemical Society, 105 (26), pp. 7516-7522.
                 DOI

4. Rajasekharan, M.V., Giezynski, S., Ammeter, J.H., Oswald, N., Michaud, P., Hamon, J.R., Astruc, D.
EPR studies of the electronic structure and dynamic Jahn-Teller effect in iron(I) sandwich compounds
(1982) Journal of the American Chemical Society, 104 (9), pp. 2400-2407.
                 DOI

3. Rajasekharan, M.V., Manoharan, P.T.
EPR studies on copper and cobalt triazene-1-oxide complexes in a frozen nematic medium.
(1980) Molecular crystals and liquid crystals, 59 (3-4), pp. 197-205.
                 DOI

2. Rajasekharan, M.V., Varughese, K.I., Manoharan, P.T.
Crystal and molecular structure of two crystalline modifications of bis[1- methyl-3-(2-chloro-6-methylphenyl)triazine 1-oxidato]nickel(II), NiBPT - A bis chelate with a five-membered Ni-N-O ring
(1979) Inorganic Chemistry, 18 (8), pp. 2221-2226.
                 DOI

1. Rajasekharan, M.V., Sethulakshmi, C.N., Manoharan, P.T., Güdel, H.
Polarized optical absorption studies on copper and silver diethyldithiocarbamates
(1976) Inorganic Chemistry, 15 (11), pp. 2657-2662.
                 DOI