Preparation of the complex:
Reagents : Al2(SO4)3.18H2O
MgO
H2C2O4.2H2O
NaOH
Ba(OH2)2.8H2O
Calculate
the amount of the reagents required to obtain about 2 g of the
product -
for this, use the formula
of the anhydrous compound - NaMgAl(C2O4)3
(Actually you may get hydrated
crystals)
To prepare the crystals, try the following:
Dissolve the oxalic acid in about 50
ml of water in a beaker. Add NaOH (solid with a little water to wash it
down).
Wait for the solution to become clear. Then add the aluminium sulphate
and
stir to dissolve. Now add the MgO and stir
till the solution becomes clear. Heat the solution on a hot plate and
add the barium hydroxide. Continue heating for
about 10 min. Let the precipitate settle down as much as possible.
Filter and collect the filtrate in a clean beaker.
Reduce the volume of the filtrate to about 10 ml by heating on a water
bath. Cool and see if any crystals form.
If not concentrate again and cool. Collect the crystals and wash with
small quantities of water. Dry between
fold of filter paper and sore in sample bottle. Try some modifications
- The aim is to get a
good yield of
well formed crystals.
NOTE: The solution should be
saturated for the crystalisation to begin. Slow cooling usually gives
larger crystals.
Initial amounts of the reagents
used must be in correct proportions. Otherwise the product may be
impure (Why?)